This article analyses the formation of emissions and their impact on the quality of the environment in the production of iron ore agglomerates with the addition of biomass. Agglomeration operations long time rang among the largest air polluters. The contemporary trend is manifested mainly by the reduction of pollutants emitted into the atmosphere; therefore, it is relevant to deal with this issue. The amount and chemical composition of harmful substances released by the production of iron ore agglomerate is affected by a large number of factors, but mainly by chemical and granulometric charge composition, amount, type and granulometry of fuel, but also technological parameters of sintering, such as negative pressure, thickness of sintered layer, charge permeability or speed and amount of sucked air. Analysis of the effect of the addition of biomass on the production of emissions in agglomeration process was carried out by experiments with laboratory sintering pan. Based on the results of laboratory sinterings, with the substitution of coke breeze by charcoal in the amounts of 8 %, 14 %, 20 %, 44 %, 50 % and 86 %, it can be stated that there was no significant over-production, or reduction of emissions of CO2 and CO when compared to coke breeze as fuel. In the case of NO and NOx emissions, there was observed some more significant reduction in the sintering with 44 %, 50 % and 86 % replacement of coke breeze by charcoal. Overall, the issue of coke breeze substitution in the agglomeration process with various types of biofuels is justified, but it should be explored in more detail.