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Polylactic Acid (PLA) is increasingly used in the oil industry and specifically for diversion in matrix acidizing as evidenced by a number of field cases recently published. The solid polyester is particularly attractive due to its ability to degrade in the presence of water and heat, negating the need for cleanup fluids or complicated procedures. A majority of the analysis on the effectiveness of PLA thus far comprises experiments on artificially created slots, filter cake analysis, and field trials. This paper demonstrates the effect of PLA in wormholes developed by acidizing outcrop cores. In these experiments, a wormhole is generated in a portion of the core by limiting the amount of acid injected. Next, the PLA is injected into the core using a heavy brine suspension. Finally, more acid is injected until a wormhole breaks through the core. Computer Tomography (CT) scans are taken, and the pressure drop across the core is recorded at each stage. Experiments were conducted for a variety of initial wormhole lengths. It can be difficult to suspend PLA while injecting it through a core in a way that is benign to the core, acid, and PLA; and in a way that does not add any pressure drop or diversion due to viscosity changes. This paper describes and justifies a suitable method of keeping PLA suspended to allow its use in core flood experiments. The CT scans show that even when the PLA plugs the wormhole, additional acid tends to continue to develop the dominant wormhole. The pressure drop profiles show that the pressure drop due to PLA injection is proportional to the mass of PLA, both in the wormhole and on the core surface. The pressure profiles also show that there is an increased pressure drop due to PLA in the wormhole versus in a filter cake on the surface. This paper details a new method of visualizing and analyzing the effect of PLA in a multistage acidizing treatment. Empirical correlations are presented for estimating the pressure drop caused by PLA, both as a filter cake on the formation surface and as a filling inside wormholes. The correlations were incorporated in a comprehensive carbonate acidizing model to predict the diversion efficiency of PLA particles. The simulation is verified using published field trials of diversion treatments.
Polylactic Acid (PLA) is increasingly used in the oil industry and specifically for diversion in matrix acidizing as evidenced by a number of field cases recently published. The solid polyester is particularly attractive due to its ability to degrade in the presence of water and heat, negating the need for cleanup fluids or complicated procedures. A majority of the analysis on the effectiveness of PLA thus far comprises experiments on artificially created slots, filter cake analysis, and field trials. This paper demonstrates the effect of PLA in wormholes developed by acidizing outcrop cores. In these experiments, a wormhole is generated in a portion of the core by limiting the amount of acid injected. Next, the PLA is injected into the core using a heavy brine suspension. Finally, more acid is injected until a wormhole breaks through the core. Computer Tomography (CT) scans are taken, and the pressure drop across the core is recorded at each stage. Experiments were conducted for a variety of initial wormhole lengths. It can be difficult to suspend PLA while injecting it through a core in a way that is benign to the core, acid, and PLA; and in a way that does not add any pressure drop or diversion due to viscosity changes. This paper describes and justifies a suitable method of keeping PLA suspended to allow its use in core flood experiments. The CT scans show that even when the PLA plugs the wormhole, additional acid tends to continue to develop the dominant wormhole. The pressure drop profiles show that the pressure drop due to PLA injection is proportional to the mass of PLA, both in the wormhole and on the core surface. The pressure profiles also show that there is an increased pressure drop due to PLA in the wormhole versus in a filter cake on the surface. This paper details a new method of visualizing and analyzing the effect of PLA in a multistage acidizing treatment. Empirical correlations are presented for estimating the pressure drop caused by PLA, both as a filter cake on the formation surface and as a filling inside wormholes. The correlations were incorporated in a comprehensive carbonate acidizing model to predict the diversion efficiency of PLA particles. The simulation is verified using published field trials of diversion treatments.
Summary Water huff ‘n’ puff is an effective enhanced oil recovery (EOR) technology for tight oil reservoirs. However, the oil production of horizontal wells declines seriously after several huff ‘n’ puff cycles, and a large amount of oil is still trapped in the reservoir due to the heterogeneity of fracturing sections. The temporary plugging agent had been used for plugging high-permeability areas and thus diverting the following fluid into small permeability areas. It would improve the sweep efficiency of flooding fluid, enhancing oil recovery. However, the use of the oil-soluble particulate temporary plugging agent in the water huff ‘n’ puff application is barely reported. Therefore, the feasibility and influencing factors of oil-soluble particulate temporary plugging agent-assisted water huff ‘n’ puff (TAWHP) in enhancing oil recovery was investigated in this study. First, based on the evaluation of the performance of the oil-soluble particulate temporary plugging agent, the oil recovery of fractured core samples with different apertures for water huff ‘n’ puff and TAWHP was compared via the parallel-core experiment to verify the feasibility of TAWHP in enhancing oil recovery. The temporary plugging agent had good oil solubility, a low residual rate in the formation, and little damage to the formation. The oil recovery yielded by TAWHP was 5.17% higher than the traditional water huff ‘n’ puff process. More oil (i.e., about 1.71%) could be expelled from the fractured core samples with a small aperture. It indicated that the EOR performance yielded by water huff ‘n’ puff after several cycles could be enhanced by adding the oil-soluble particulate temporary plugging agent. After that, a mathematical model of TAWHP was established to investigate the effect of TAWHP parameters on EOR performance. The simulation results showed that the cumulative oil production increased with the increase in injection time of the temporary plugging agent solution, but the trend would level-off after 10 minutes. Moreover, as the diversion index increased, the effect of the injection rate on cumulative oil production gradually enhanced while the effect of the soaking time gradually weakened. Furthermore, the difference in cumulative oil production at different diversion indexes gradually increased as the huff ‘n’ puff cycle increased. This work could provide theoretical guidance for water huff ‘n’ puff enhancing oil recovery after several cycles.
A known challenge in carbonate acid stimulation is achieving a uniform acid distribution in long wells along a heterogeneous reservoir. Completion strategies such as running a limited-entry-liner may not be sufficient to achieve the desired conformance. In recent years, degradable solids have become one of the most common diverters for acid stimulation. However, their behavior in uncemented completions is not well understood. In this study, parallel dual-core flow tests were conducted to evaluate the impact of completion type (cased hole vs. open hole) on diverter efficiency. In the dual-core flow setup, two limestone cores with a permeability ratio of 30:1 were used, and experiments consisted of three main flow stages. First, 15wt% HCl was injected, which tended to create a wormhole in the high-perm core. A specified volume of a solids diverter slurry was then injected to improve the flow distribution. The final stage consisted of injecting 15wt% HCl until breakthrough. The flow rate of each core was recorded throughout the test to evaluate the diversion effect for both open hole and cased hole completion scenarios. CT scans of both cores were obtained to visualize the wormhole geometry after each acid stage. Test results showed significantly different diverter performance for the cased hole vs. open hole scenarios, leading to insightful guidelines on diverter efficiency depending on completion type. After the first acid stage, a dominant wormhole was created in the high-perm core only, mainly due to the large permeability ratio. This behavior was very similar for both completion scenarios. In the open-hole test, the diverter formed an external filter cake on the injection face of the high-perm core. The second acid stage easily broke through this external filter cake and continued to propagate the original wormhole. As a result, acid diversion was limited, and a relatively short wormhole was created in the low-perm core. However, in the cased-hole test, a relatively higher volume of diverter entered the perforation / wormhole structure, leading to a more effective diversion and hence a more even stimulation of both cores after the second acid stage was injected. The large-scale dual core flow setup in this study is the first of its kind and using it in conjunction with the implemented workflow has provided valuable insights into how various completion types will impact solids diverter efficiency during matrix acid stimulation. As completion lengths continue to get longer, a good understanding of solids diverter efficiency, especially for open hole completions currently being implemented in the Middle East, is necessary to develop reliable models that can be used for a more effective treatment design.
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