This work aims at investigating the possible advantages of substituting the mixer in traditional SCR systems with an Electrically Heated Catalytic structure (EHC). First of all, EHC technology is being widely investigated in literature because it offers a concrete solution for catalyst thermal activation and film formation reduction in engine cold start conditions; however, its adoption as a mixer can also guarantee other important improvements in reducing pollutant emissions. In this work, a low-pressure injection of Ad-Blue impacts an electrically heated structure and a complete analysis of liquid droplets and film evaporation is carried out. A hybrid Eulerian-Lagrangian model has been adopted on a multi-region configuration, accounting for fluid-solid conjugate heat transfer (CHT), which plays a key role in the conversion strategy: it has been demonstrated that the heated structure can be exploited to significantly increase the exhaust gas enthalpy in the cold start, which represents an important improvement for pollutant conversion. Different heating strategies are analysed, with the objective of maximising the spray evaporation and the uniformity of the ammonia distribution downstream of the mixer. The objectives of this work are emphasizing the improvements that an electrically heated mixing catalyst can bring to the traditional SCR configuration, laying the foundation for other following studies.