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An understanding of the physical properties of hydrate-bearing sediments is important for interpretation of geophysical data collected in field settings, borehole and slope stability analyses, and reservoir simulation and production models. Yet current knowledge of geophysical and geotechnical properties of hydratebearing sediments is still largely derived from laboratory experiments conducted on disparate soils at different confining pressures, degrees of water saturation, and hydrate concentrations. Here we report on the key findings that have emerged from 5 years of laboratory experiments conducted on synthetic samples of sand, silts, or clays subjected to various confining pressures in standardized geotechnical laboratory devices and containing carefully controlled saturations of tetrahydrofuran hydrate formed from the dissolved phase. For the first time, we use this internally-consistent data set to conduct a comprehensive analysis of the trends in geophysical and geotechnical properties as a function of hydrate saturation, soil characteristics, and other parameters. Our experiments emphasize measurements of seismic velocities, electrical conductivity and permittivity, large strain deformation and strength, and thermal conductivity. We discuss the impact of hydrate formation technique on the resulting physical properties measurements and use our data set to identify systematic effects of sediment characteristics, hydrate concentration, and state of stress, extracting robust relationships (often based on micromechanical concepts) for the most relevant material parameters. The mathematical trends that emerge for the measured physical parameters always require that the hydrate saturation in pore space, which ranges from 0 to 1, be raised to a power greater than 1. This significantly reduces the impact of low hydrate saturations on the measured physical parameters, an effect that is particularly pronounced at the hydrate saturations characteristic of many natural systems (<0.2 of pore space). The results also reveal that the electrical properties of hydrate-bearing sediments are less sensitive to the method used to form hydrate in the lab (which controls the pore-scale arrangement of hydrate and sediment grains) than to hydrate saturation. Mechanical properties are strongly influenced by both soil properties and the hydrate loci. Thermal conductivity depends on the complex interplay of a variety of factors, including formation history, and cannot be easily predicted by volume average formulations.
An understanding of the physical properties of hydrate-bearing sediments is important for interpretation of geophysical data collected in field settings, borehole and slope stability analyses, and reservoir simulation and production models. Yet current knowledge of geophysical and geotechnical properties of hydratebearing sediments is still largely derived from laboratory experiments conducted on disparate soils at different confining pressures, degrees of water saturation, and hydrate concentrations. Here we report on the key findings that have emerged from 5 years of laboratory experiments conducted on synthetic samples of sand, silts, or clays subjected to various confining pressures in standardized geotechnical laboratory devices and containing carefully controlled saturations of tetrahydrofuran hydrate formed from the dissolved phase. For the first time, we use this internally-consistent data set to conduct a comprehensive analysis of the trends in geophysical and geotechnical properties as a function of hydrate saturation, soil characteristics, and other parameters. Our experiments emphasize measurements of seismic velocities, electrical conductivity and permittivity, large strain deformation and strength, and thermal conductivity. We discuss the impact of hydrate formation technique on the resulting physical properties measurements and use our data set to identify systematic effects of sediment characteristics, hydrate concentration, and state of stress, extracting robust relationships (often based on micromechanical concepts) for the most relevant material parameters. The mathematical trends that emerge for the measured physical parameters always require that the hydrate saturation in pore space, which ranges from 0 to 1, be raised to a power greater than 1. This significantly reduces the impact of low hydrate saturations on the measured physical parameters, an effect that is particularly pronounced at the hydrate saturations characteristic of many natural systems (<0.2 of pore space). The results also reveal that the electrical properties of hydrate-bearing sediments are less sensitive to the method used to form hydrate in the lab (which controls the pore-scale arrangement of hydrate and sediment grains) than to hydrate saturation. Mechanical properties are strongly influenced by both soil properties and the hydrate loci. Thermal conductivity depends on the complex interplay of a variety of factors, including formation history, and cannot be easily predicted by volume average formulations.
The process of drilling in natural gas hydrate reservoirs in sea areas involves problems such as hydrate decomposition and wellbore instability. To study the response behaviors of a reservoir during the drilling process, a two-dimensional numerical model of drilling fluid invading a hydrate reservoir in a cylindrical coordinate system was established to simulate the processes of heat and mass transfer, gas–liquid two-phase flow, and hydrate formation and decomposition in the hydrate reservoir during the drilling process. Based on the hydrate reservoir at station W17, Shenhu area of the South China Sea, the physical property response of the hydrate reservoir under different drilling fluid temperatures and salinity values was studied. The simulation results showed that during the drilling process, the temperature and pressure of the reservoir respond rapidly in a large area, further promoting the hydrate decomposition in the reservoir around the wellbore and leading to secondary hydrate formation. Moreover, a high hydrate saturation zone appears near the decomposed hydrate area in the layer without free gas, which corresponds to the low water saturation and high salinity zone. The hydrate decomposition area in the layer with free gas is larger than that without free gas. The increase in the drilling fluid temperature significantly enhances the hydrate decomposition in both layers of the reservoir. The hydrate decomposition near the wellbore under the high drilling fluid temperature will cause a sharp increase in the pressure in the reservoir, leading to the flow of pore fluid into the wellbore. The increase in drilling fluid salinity has little effect on the range of the hydrate decomposition in the reservoir but significantly increases the salinity of the pore water in the layer with free gas. As the drilling fluid temperature increases, the possibility of the gas invasion from the reservoir into the wellbore will be greatly increased at the early stage.
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