“…Ferroelectrics hold the promise to revolutionize low‐power logic, nonvolatile memories, actuators, sensors, and electro‐optics for waveguide devices. [ 1–24 ] These applications require suitable control and manipulation of ferroelectric domains and domain walls in ferroelectric thin films. Since 180° polarization switching was accomplished in 4.8 nm thick tetragonal BaTiO 3 thin films via mechanical manipulation, [ 25 ] considerable effort has been devoted to manipulating the polarization switching in ferroelectric thin films, for example, 3–5 nm thick PbZr 0.2 Ti 0.8 O 3 (001) film, 1.6–45 nm thick BaTiO 3 (001) film, 50 nm thick PbZr 0.1 Ti 0.9 O 3 (001) film, and 10 nm thick PbZr 0.48 Ti 0.52 O 3 (001) film, and flexoelectric effect is proposed to explain the mechanical manipulation of the domain and domain wall structures.…”