The study of dynamic systems appears in various aspects of dynamical structures such as decomposition, decoupling, observability, and controllability. In the present research, we study the controllability of fractional stochastic systems (FSF) and examine the Poisson jumps in finite dimensional space where the fractional impulsive neutral stochastic system is controllable. Sufficient conditions are demonstrated with the aid of fixed point theory. The Mittag-Leffler (ML) matrix function defines the controllability of the Grammian matrix (GM). The relation to symmetry is clear since the controllability Grammian is a hermitian matrix (since the integrand in its definition is hermitian) and this is the complex version of a symmetric matrix. In fact, such a Grammian becomes a symmetric matrix in the specific scenario where the controllability Grammian is a real matrix. Some examples are provided to demonstrate the feasibility of the present theory.