Modelling methanol conversion to hydrocarbons: Alternative kinetic models

Catalyst Deactivation by Coke in the Transformation of Aqueous Ethanol into Hydrocarbons. Kinetic Modeling and Acidity Deterioration of the Catalyst

“…17,[28][29][30][31][32] One difference is the convenience of taking ethene as a differentiated component from the remaining components and lumps in the reaction medium.…”

Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor

“…The kinetic models presented in the literature consist almost of first-order reaction rates, only second-order rates can be found sometimes [11][12][13][14][15][16][17][18][19]30,31]. This implies that there is no concentration dependence on the product distribution, but our measurements have shown the opposite.…”

“…However, some aspects have not been regarded in the individual models. Most models have been proposed for MTG-process conditions with temperatures below 400°C [11][12][13]30,31]. Furthermore, the simplification of the kinetic scheme does not allow the differentiation of the light olefins, because they were grouped together [11][12][13][14][15]17,18].…”

Synthesis gas conversion into hydrocarbons (gasoline range) over bifunctional zeolite-containing catalyst: experimental study and mathematical modelling

“…The model satisfactorily describes the reaction products distribution as regards paraffins, aromatics, olefins and oxygenates in the temperature range 302-370 • C within a wide range of conversions. In [7], three lumped kinetic models were developed and tested for the same temperature range, describing ethylene, propylene, butylenes and paraffins forming from oxygenates (methanol and DME). Michail …”

“…Many investigations are focused on studying the kinetic regularities of methanol conversion into hydrocarbons [6][7][8][9][10]. One of the first models has been proposed by Chang [5].…”