Please cite this article as: Mamdouh Omran, Timo Fabritius, Effect of steelmaking dust characteristics on suitable recycling process determining: Ferrochrome converter (CRC) and electric arc furnace (EAF) dusts, Powder Technology (2016),
AbstractUtilization of dusts generated from steelmaking industries will avoid disposal of wastes, enhance the use of secondary raw material fines and save costs. Understanding the properties of dust is necessary before determining the suitable recycling method. The present paper describes the chemical, morphological and mineralogical characterization of steelmaking dusts produced in steel plants in Finland. In this paper three different steelmaking dusts: ferrochrome converter (CRC) and electric arc furnace stainless steel (EAFSS) dusts from Outokumpu (Tornio, Finland), and electric arc furnace carbon steel (EAFCS) dust from Ovako (Imatra, Finland) were characterized.The characterization study showed that, the dusts from carbon steelmaking (EAFCS) are rich in zinc, while the dusts from stainless steelmaking (CRC) and (EAFSS) are relatively low in zinc, but richer in chromium. The zinc contents in CRC, EAFSS and EAFCS dusts are 10.83, 19.84 and 35.76 wt.%, respectively, while the chromium contents are 20.88, 3.19 and 0.47 wt.%, respectively.In the dust from CRC, zinc is found as zinc oxide (zincite, ZnO), while in the dusts from EAFSS & EAFCS zinc is found mostly as zinc ferrite (franklinite, ZnFe 2 O 4 ). Scanning electron microscopy (SEM) investigations indicated that CRC dust is dominated by non-spherical form and composed mainly of aggregates of irregular particles of chromite, in addition to zincite sphere. EAFSS dust particles are characterized by encapsulation phenomenon, franklinite particles enclosed inside calcium-iron-silicate glass sphere. Manganese (Mn) concentrations shows positive correlation with
ACCEPTED MANUSCRIPTZn, which suggests the occurrence of Mn mainly with franklinite phase. EAFCS dust is dominated by spherical form, and zinc found as franklinite and zincite. In the large particles > 3 µm of EAFCS dust, franklinite enclosed inside glass sphere, while in finer particles < 1 µm, both zincite and franklinite are existed as spheres.The investigations indicate that steelmaking dusts from CRC, EAFSS, and EAFCS show significant difference in concentration and mode of occurrence of zinc in the dusts, which will influence on determine the suitable processing methods.There are different types of steelmaking dusts generated from steel industries [1, 2], depending on process unit: stainless steel dust, carbon steel dust and ferrochrome dust. These dusts are by-product waste generated by the secondary steelmaking process in an electric arc furnace and considered as a hazardous waste in most industrialized countries [3, 4]. During the melting of scraps in the electric arc furnace (EAF), many components of the charge including iron, zinc, and lead, are volatilized and entered the vapour phase. The dust is formed through the conversion of vapour phases into dust by agglo...