Modelling photo-Fenton process for organic matter mineralization, hydrogen peroxide consumption and dissolved oxygen evolution

Cabrera‐Reina, Alejandro; Santos‐Juanes, Lucas; Sánchez, José Francisco Fernandez; López, J.L. Casas; Pérez, J.A. Sánchez

doi:10.1016/j.apcatb.2012.02.021

Cited by 37 publications

(19 citation statements)

References 28 publications

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“…classical Fenton process [9][10][11][12][13][14][15][16], Fenton-like treatment [17][18][19] and photo-Fenton process [20][21][22]. However, only two papers refer to electro-Fenton process [23,24].…”

Section: Ar(hoh) • + O 2 → Ar(oh) + Homentioning

confidence: 94%

A complete phenol oxidation pathway obtained during electro-Fenton treatment and validated by a kinetic model study

Mousset¹,

Frunzo

Esposito

et al. 2016

Applied Catalysis B: Environmental

156

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Section: Ar(hoh) • + O 2 → Ar(oh) + Homentioning

confidence: 94%

A complete phenol oxidation pathway obtained during electro-Fenton treatment and validated by a kinetic model study

Mousset¹,

Frunzo

Esposito

et al. 2016

Applied Catalysis B: Environmental

156

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“…Regarding the empirical models, in literature, it is possible to find preliminary works proposing the use of response surface platform for regression models (Pérez-Moya et al 2008). More recently, semi-empirical models combining a first principles modeling approach with empirical observations have been proposed by Cabrera Reina et al (2012Reina et al ( , 2015. Finally, advanced multivariate techniques named data-based modeling (DBM) can also be found (Shokry et al 2015(Shokry et al , 2017.…”

Section: Introductionmentioning

confidence: 99%

A novel modeling approach for a generalizable photo-Fenton-based degradation of organic compounds

Audino

Pérez-Moya

Graells

et al. 2020

Environ Sci Pollut Res

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This work aims at proposing and validating a model that can be exploited for the future development of industrial applications (e.g., process design and control) of Fenton and photo-Fenton processes. Hence, a compromise modeling solution has been developed between the non-generalizable accuracy of the first principles models (FPMs) and the oversimplification of the empirical models (EMs). The work presents a novel model of moderate complexity that is simplified enough to be generalizable and computationally affordable, while retaining physical meaning. The methodology is based on a general degradation mechanism that can be algorithmically generated from the carbon number of the target compound, as well as from the knowledge of two kinetic parameters, one for the faster initial rate and the other one for the subsequent degradation steps. The contaminant degradation mechanism has been combined with an appropriately simplified implementation of the well-known Fenton and photo-Fenton kinetics. This model describes the degradation not only of the target compound and of the oxidant, but also of total organic carbon (TOC), which is used to define the overall quality of the water. Experimental design techniques were used along with a non-conventional modeling methodology of programmable process structures (PPS). This novel modeling approach was applied and validated on the degradation of three model compounds. A successful prediction of the evolution of the contaminants H 2 O 2 and TOC was confirmed and assessed by the root mean square error (RMSE).

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“…26. This strategy has been used in previous work (Cabrera Reina et al, 2012 The subscript i stands for each identification run; t is the time when the variable was measured; sim stands for the simulated value; and exp, for the measured value; is a weighting parameter to define the contribution and importance of each parameter to the model. The value of alpha was 4, 2, 1 and 3 for ACTM, TBZ, IMZ and hydrogen peroxide, respectively.…”

Section: Modellingmentioning

confidence: 99%

“…This is especially difficult for a solar-driven process, where irradiance is an environmental variable which cannot be controlled. Some attempts have been tried at higher pollutant concentrations (Cabrera Reina et al, 2012;Kusic et al, 2009;Li Puma et al, 2004), but as far as the authors know, not for micropollutants.…”

Section: Introductionmentioning

confidence: 99%

Modelling micropollutant removal by solar photo-Fenton

Carra

Sánchez²,

Malato³

2014

Global NEST Journal

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This paper is focused on modelling the degradation of micropollutants by solar photo-Fenton at pilot plan scale. To this aim, a three pesticide mixture (acetamiprid, thiabendazole and imazalil, 100 μg l ). A Monte Carlo direct search was used to determine the kinetic constants which adjusted pesticide removal and hydrogen peroxide consumption in the selected experimental conditions (identification runs). The model was validated with experimental conditions different from the identification step (validation runs). Hydrogen peroxide consumption and pollutant degradation could be predicted adequately for all irradiances and iron concentrations higher than 5 mg l -1 Fe. As a result, the presented model could predict the treatment time during the whole year, as it is valid for a wide range of irradiation and for commonly used values of catalyst concentration.

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Modelling photo-Fenton process for organic matter mineralization, hydrogen peroxide consumption and dissolved oxygen evolution

Cited by 37 publications

References 28 publications

A complete phenol oxidation pathway obtained during electro-Fenton treatment and validated by a kinetic model study

A complete phenol oxidation pathway obtained during electro-Fenton treatment and validated by a kinetic model study

A novel modeling approach for a generalizable photo-Fenton-based degradation of organic compounds

Modelling micropollutant removal by solar photo-Fenton

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