Alley cropping is a specific agroforestry system, which is regarded as sustainable land use management, that could play a crucial role in climate change adaptation and mitigation. Despite its appealing attributes, farmers’ up-take of the system is slow in temperate regions. This study aims to contribute to scaling-up agroforestry through a case study in Hungary and to help to design productive alley cropping systems. We investigated which tree planting pattern of black locust (Robinia pseudoacacia L.) results in the most productive alley cropping system when intercropped with triticale (x Triticosecale W.) by statistically analysing the yields of the intercrop and of the trees in nine different layouts and by calculating land equivalent ratios (LER). There was significant difference between the treatments both in triticale and black locust yields. The more trees planted on a hectare, the higher the volume of the stand, and the less yield of triticale was observed, although the latter correlation was weak and in some cases the triticale was more productive between the trees compared with sole crop control. Eight out of nine treatments had favourable LER (0.94–1.35) when the trees were five years old. Black locust and triticale seem to be a good combination for productive alley cropping systems.