2022
DOI: 10.1088/1361-648x/ac51ff
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Models of Ni- and Co-ion occupation in LiNi0.5Co0.5PO4 orthophosphate and its magnetic structure

Abstract: The neutron diffraction, magnetic and heat capacity measurements have been carried out to study the polycrystalline sample LiNi0.5Co0.5PO4 prepared by the glycerol-nitrate synthesis method. Models of Ni- and Co-ion occupation the 4с octahedral position in a crystal structure LiNi0.5Co0.5PO4 are calculated for a paramagnetic state. The best model is the Ni- and Co-ions occupy the 4с site in Pnma patent space-group in sequence Ni-Co-Ni-Co or Co-Ni-Co-Ni. It is shown that nickel ions form ab planes alternating … Show more

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