The last two decades have seen a growing trend toward the use of inorganic binders in core making for the metalcasting field. Despite the health and environmental benefits of the inorganic binders, wider commercial use requires ongoing technical improvements to address some potential inherent limitations of this technology. Considering that inorganic cores can suffer from storage stability, this study sets out to check whether inorganic core binders are fit to replace organic ones in producing a gravity diecasting Al alloy component. First, the humidity resistance of both organic and inorganic sand cores, within a typical time-frame storage in the foundry, was evaluated by moisture absorption tests. Then, 3D optical measurements were performed to assess the relative dimensional changes of inorganic cores. Last, the influence of the core system was analyzed through microstructural and mechanical investigations on castings manufactured by using organic and inorganic binders. The experimental findings have shown that the moisture absorption during storage in the foundry warehouse, which lasted up to 14 days, was not enough to jeopardize the functionality of the cores. Furthermore, the tensile and microstructural outcomes revealed that inorganic cores could comply with both high component design requirements and even more stringent environmental regulations of foundries.