Modification of the Zn–Co double metal cyanide complex for the synthesis of carbon dioxide–derived poly(ether–carbonate) polyols

Wang, Qin; Zhang, Yuanping; Li, Xiaoyun; Chen, Qian; Kang, Maoqing; Li, Qifeng; Wang, Junwei

doi:10.1016/j.jcou.2024.102768

Journal of CO2 Utilization

2024

DOI: 10.1016/j.jcou.2024.102768

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Modification of the Zn–Co double metal cyanide complex for the synthesis of carbon dioxide–derived poly(ether–carbonate) polyols

Qin Wang,

Yuanping Zhang,

Xiaoyun Li

et al.

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2024

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Synthesis, Structure, and Actual Applications of Double Metal Cyanide Catalysts

Nifant’ev,

Ivchenko

2024

IJMS

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Double metal cyanide (DMC) complexes represent a unique family of materials with an open framework structure. The main current application of these complexes in chemical industry is their use as catalysts (DMCCs) of the ring-opening polymerization of propylene oxide (PO), yielding branched polyols, highly demanded in production of polyurethanes and surfactants. The actual problem of chemical fixing carbon dioxide from the atmosphere gave new impetus to the development of DMCCs, which turned out to be effective in oxirane/CO2 copolymerization. In recent years, new types and formulations of DMCCs were created, so that greater understanding of the reaction mechanisms was achieved and new fields of catalytic applications were found. In the present review, we summarized background and actual information about the synthesis, structure, and mechanisms of the action of DMCCs, as well as their application in the development of new materials and fine chemicals.

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Synthesis, Structure, and Actual Applications of Double Metal Cyanide Catalysts

Nifant’ev,

Ivchenko

2024

IJMS

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Modification of the Zn–Co double metal cyanide complex for the synthesis of carbon dioxide–derived poly(ether–carbonate) polyols

Cited by 1 publication

References 48 publications

Synthesis, Structure, and Actual Applications of Double Metal Cyanide Catalysts

Synthesis, Structure, and Actual Applications of Double Metal Cyanide Catalysts

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