Modification on antibacterial activity of PVC/PVDF blend filled with CuO NPs using laser ablation technique

Abstract

Nanocomposite of polyvinyl chloride (PVC)/polyvinylidene fluoride (PVDF) have been in situ synthesized. Copper oxide nanoparticles (CuONPs) have been prepared via using the laser ablation technique. Nanoparticles were added to the blend. The properties of the blend were studied before and after adding CuONPs. These properties were characterized by different techniques. Antimicrobial activity of the prepared nanocomposite film was investigated. FTIR data show vibrational spectral bands and the shift of the bands is related to the interaction and the complexation that occurs between blend and nanoparticles. Structural properties and crystallinity of the samples were investigated using XRD diffraction. XRD results illustrated the effect of CuONPs at two new peaks 2θ = 26.25º and 38.41º. These results confirmed the interaction CuO NPs and PVDF/PVC matrix. UV–Visible analyses confirmed the existing of copper oxide nanoparticles and were also used for determining the optical absorption edge. The absorption edges have been obtained at 430–520 nm for all of the doping films. The obtained values for indirect and direct bandgaps were reduced by raising the nanoparticles because of the presence of charge transfer between PVC/PVDF and CuONPs. SEM images illustrateed the presence of CuONPs on the surface of the blend and the morphology changes which occurred to the blend. The antibacterial activity for the nanocomposite proved the antimicrobial effect of copper oxide nanoparticles. The prepared PVC/PVDF/CuONPs are potentially suggesting to be applied for biomedical applications.

Clay-reinforced PVC composites and nanocomposites

“…Incorporation of Ag NPs-modified chitosan into the polyacrylamide-gelatin network and coating the nanocomposite on the surface of PVC was shown to be promising to prevent biofilm-related infections in the endotracheal tube which is an essential medical device to secure the airway patency in patients undergoing mechanical ventilation or general anesthesia [ 170 ]. Composites of PVC with other nanoparticles such as CuO NPs [ 171 ], Ag NPs [ [172] , [173] , [174] ], ZnO NPs [ 175 , 176 ], modified SiO 2 nanoparticles [ 177 ], silver phosphate NPs [ 178 ] gold NPs [ 179 ], Cu NPs [ 180 ], and SiO 2 –Ag [ 181 ] have shown antibacterial activities. In the context of PVC-clay nanocomposites, clay enhances the antibacterial drug loading through electrostatic attraction and intercalation of the drug within its layers.…”