Modification Strategies of Hexagonal Boron Nitride Nanomaterials for Photocatalysis

Abstract

Although hexagonal boron nitride (h‐BN) was initially considered a less promising photocatalyst due to its large band gap and apparent chemical inertness, its unique two‐dimensional lamellar structure coupled with high stability and environmental friendliness, as the second largest van der Waals material after graphene, provides a unique platform for photocatalytic innovation. This review not only highlights the intrinsic qualities of h‐BN with photocatalytic potentials, such as high stability, environmental compatibility, and tunable bandgap through various modification strategies but also provides a comprehensive overview of the recent advances in h‐BN‐based nanomaterials for environmental and energy applications, as well as an in‐depth description of the modification methods and fundamental properties for these applications. In addition, we discuss the challenges and prospects of h‐BN‐based nanomaterials for future photocatalysis.