Abstract:The dispersion of particulate porous solids in size-excluded liquids has emerged as a method to create Type III porous liquids, mostly using insoluble microporous materials such as metal-organic frameworks (MOFs) and zeolites. Here, we present the first examples of Type III porous liquids based on porous organic cages (POCs). By exploiting the solution processability of the POCs, racemic and quasiracemic cage microparticles were formed by chiral recognition. Dispersion of these porous microparticles in a range… Show more
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