2022
DOI: 10.1039/d1tc05292f
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Modulating TTA efficiency through control of high energy triplet states

Abstract: An ideal annihilator in triplet-triplet annihilation photon upconversion (TTA-UC) can achieve a maximum of 50% quantum efficiency. This spin statistical limit depends on the energies of triplet states of the...

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Cited by 12 publications
(25 citation statements)
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“…For example, the peak absorption wavelengths of unsubstituted perylene in the nonpolar solvent toluene is ~438 nm (see, e.g., refs. [ 24 , 30 ]) and in the polar solvent acetonitrile is ~434 nm (ref. [ 25 ]).…”
Section: Resultsmentioning
confidence: 99%
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“…For example, the peak absorption wavelengths of unsubstituted perylene in the nonpolar solvent toluene is ~438 nm (see, e.g., refs. [ 24 , 30 ]) and in the polar solvent acetonitrile is ~434 nm (ref. [ 25 ]).…”
Section: Resultsmentioning
confidence: 99%
“…Taking the energy difference between the lowest-energy absorption and highest-energy fluorescence emission bands (that correspond to the most-intense absorption and fluorescence emission bands), a value of ~420 cm −1 is obtained for the Stokes shift. Literature reports a much smaller Stokes shift of 260 cm −1 for perylene in both acetonitrile and toluene [ 24 , 25 , 29 ]. It is possible that the larger Stokes shift observed in the DNA-templated perylene arises from: (i) a break in the symmetry of perylene with the addition of the ethynyl linker and uracil nucleobase, or (ii) the incorporation of perylene into the DNA HJ nanostructure [ 69 , 70 ].…”
Section: Resultsmentioning
confidence: 99%
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