YBa2Cu3O6+x
nanopowder, prepared by the citrate sol–gel method, is segregated by
sedimentation in ethanol into three size groups with average particle heights of
0.7, 1.6 and 2.3 nm. The structural properties and composition of the powders,
investigated by x-ray diffraction, atomic force microscopy, Auger electron
spectroscopy and EPR-spectroscopy, show no clear differences, except the
size. According to investigations by magnetometry and by non-resonant
microwave absorption the as-prepared powder contains weak links which,
however, disappear during the segregation. The magnetic susceptibility
of the samples decreases with the decreasing particle size, in agreement
with the susceptibility values calculated from the London equations for
cylindrical particles smaller than the London penetration depth. In all three
size groups the critical temperature of superconductivity is 92 K.