MOF-derived hierarchical porous carbon octahedrons for aluminum-ion batteries

Wang, Lei; Zhu, Guoyin; Lin, Yu‐Chi; Wang, Yi; Zhu, Qinshu; Dai, Zhihui

doi:10.1016/j.carbon.2022.10.069

Cited by 21 publications

(3 citation statements)

References 49 publications

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“…Tremendous investigation have revealed that chemical reactions primarily occur on the inner walls of pores [53]. Increasing the porosity and specific surface area is favorable to enhance the physicochemical properties of the material.…”

Section: Preparation Methods Of Hpcmentioning

confidence: 99%

Hierarchical porous carbon materials for lithium storage: preparation, modification, and applications

Ying,

Yin,

Zhao

et al. 2024

Nanotechnology

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Secondary battery as an efficient energy conversion device have been highly attractive for alleviating the energy crisis and environmental pollution. Hierarchical porous carbon materials with multiple sizes pore channels are considered as promising materials for energy conversion and storage applications, due to their high specific surface area and excellent electrical conductivity. Although many reviews have reported on carbon materials for different fields, systematic summaries about hierarchical porous carbon materials for lithium storage are still rare. In this review, we fist summarize the main preparation methods of hierarchical porous carbon materials, including hard template method, soft template method, and template-free method. The modification methods including porosity and morphology tuning, heteroatom doping, and multiphase composites are introduced systematically. Then, the recent advances in hierarchical porous carbon materials on lithium storage are summarized. Finally, we outline the challenges and future perspectives for the application of hierarchical porous carbon materials in lithium storage.

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Section: Preparation Methods Of Hpcmentioning

confidence: 99%

Hierarchical porous carbon materials for lithium storage: preparation, modification, and applications

Ying,

Yin,

Zhao

et al. 2024

Nanotechnology

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show abstract

“…A hierarchical porous carbon octahedron (HPCO) derived from Cu‐based MOFs was also prepared. The hierarchical porous structure was conducive to electrolyte penetration and the HPCO maintained a capacity of 60.8 mAh g −1 after 200 cycles [11] . Xiao et al.…”

Section: Introductionmentioning

confidence: 99%

“…The hierarchical porous structure was conducive to electrolyte penetration and the HPCO maintained a capacity of 60.8 mAh g À 1 after 200 cycles. [11] Xiao et al carbonized ZIF-67 at 700 °C with sulfur powders for AlÀ S battery. The Co-based MOFs maintained a good polyhedral morphology, inhibited harmful dissolution and shuttle effect.…”

Section: Introductionmentioning

confidence: 99%

A Pyramidal Metal–Organic Frameworks‐Derived FeP@CoP Aluminium‐Ion Battery Cathode Displaying Low‐Temperature Tolerance and Fast Electron Transfer Kinetics

Bai

Tao

Yan

et al. 2023

Chemistry A European J

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Anhui Provincial Engineering Laboratory for Engineering appropriate cathode materials is significant for the development of high-performance aluminum-ion (Al-ion) batteries. Here, a pyramidal metal-organic frameworks (MOFs)-derived FeP@CoP composite was developed as cathode, which exhibits good stability and high capacity. FeP@CoP cathode maintains a high capacity of 168 mAh g À 1 after 200 cycles, and displays a stable rate-performance at both room and low temperatures of À 10 °C. After three rounds of rate-performance cycling, the FeP@CoP composite recovers 178.2 mAh g À 1 at 0.3 A g À 1 . Moreover, density functional theory (DFT) calculations verify improved electrontransfer kinetics with narrowed band gap and enhanced density of states. These findings inspire a broad set of studies on MOFs-derived composites for high-performance secondary batteries.

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Recent Advances of Metal‐Organic Frameworks and Derivatives for Rechargeable Aluminum Batteries

Wang,

Choo,

et al. 2024

SusMat

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In light of cost‐effectiveness, high volumetric capacity, and abundant supplies on Earth of aluminum metal, the rechargeable aluminum battery (RAB) represents a cutting‐edge alternative for energy storage devices. RABs have achieved significant progress as a result of tireless efforts; however, challenges like as expensive ionic liquid electrolytes, a restricted voltage window of aqueous electrolytes, corroded anode, and rapid capacity degradation limit their practical applications. In terms of increasing RAB mileage, electrode materials can be regarded as the foundation of battery performance. Metal‐organic frameworks (MOFs), which have customizable topologies, multiple active sites, and various metal centers and ligands, are promising electrode materials. Herein, for the first time, we deliver in detail the recent advancement of MOFs in RABs. The relationship on structure‐properties‐performance of MOFs is thoroughly discussed. MOF and MOF‐derived electrode materials are first summarized. In aluminum sulfur/selenium batteries, MOF can serve as a host to capture the sulfides or selenides. Furthermore, the MOF as catalysts for aluminum‐air batteries are provided. Then we focused on the challenges and opportunities that RABs would face in the future, and some prospects are presented. We believe this account will facilitate the exploration of MOFs in RABs and give more inspiration for discovering advanced RABs.

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MOF-derived hierarchical porous carbon octahedrons for aluminum-ion batteries

Cited by 21 publications

References 49 publications

Hierarchical porous carbon materials for lithium storage: preparation, modification, and applications

Hierarchical porous carbon materials for lithium storage: preparation, modification, and applications

A Pyramidal Metal–Organic Frameworks‐Derived FeP@CoP Aluminium‐Ion Battery Cathode Displaying Low‐Temperature Tolerance and Fast Electron Transfer Kinetics

Recent Advances of Metal‐Organic Frameworks and Derivatives for Rechargeable Aluminum Batteries

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