MOF-derived Ni@NC catalyst: synthesis, characterization, and application in one-pot hydrogenation and reductive amination

Abstract

MOF-derived Ni@NC is prepared and used as highly selective catalyst for one-pot hydrogenation and reductive amination.

Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition

“…12,[18][19][20] This gives access to an exceptional freedom to tune and optimize the properties of catalysts synthesized by this rather new strategy. The decomposition of metal-organic frameworks has already been used to create catalytically active nanoparticles, 21,22 electrode materials, 23,24 nanoporous carbon materials 25 and hybrid supercapacitors. 26 To our knowledge, energy-related applications of such materials have rarely been studied.…”

Recent Advances on Heteroatom‐Doped Porous Carbon/Metal Materials: Fascinating Heterogeneous Catalysts for Organic Transformations

“…First, Ni‐MOF‐NH 2 was synthesized by a solvothermal method using nickel nitrate hexahydrate and 2‐aminoterephthalic acid as precursors and subsequently carbonized at various temperatures and times ranging from 400 to 700 °C and 1–2 h (Figure 49). [139] …”

Metal-based Heterogeneous Catalysts for One-Pot Synthesis of Secondary Anilines from Nitroarenes and Aldehydes

“…In 2019 Wang and Chen prepared a MOF-derived catalyst with nickel nanoparticles (6–7 nm in size) uniformly embedded in nitrogen doped carbon shells [ 104 ], following roughly the strategy already introduced by Beller and discussed in the above reported paragraphs. In details, the new catalyst was obtained by mixing 2-aminoterephthalic acid and polyvinylpyrrolidone with a nickel(II) salt in DMF/water, thus obtaining a green solid precipitate (Ni-MOF-NH 2 ), which was pyrolyzed at 600 °C for 1.5 h under Ar to get the final Ni@NC-600-1.5 catalyst.…”