MOF-derived transition metal-based catalysts for the electrochemical reduction of CO<sub>2</sub>to CO: a mini review

Li, Jiaxin; Zhang, Baogang; Dong, Bao‐Xia; Feng, Ligang

doi:10.1039/d3cc00451a

Cited by 18 publications

(2 citation statements)

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“…Furthermore, the incorporation stabilizes the created sites and formulates synergistic reaction conditions that highly utilize the substrate molecules in improving CO 2 conversion efficiency. [138] To enhance catalytic activity and search for a stable catalyst that works in harsh conditions in eCO 2 RR, MOF-derivatives have attracted huge research attention.…”

Section: Mof Derivatives For Eco 2 Rrmentioning

confidence: 99%

Metal‐Organic Frameworks for Efficient Electrochemical Reduction of Carbon Dioxide

et al. 2023

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The large concentration of carbon dioxide (CO2) in the atmosphere can be utilized in industrial production using effective electrocatalysts such as metal‐organic frameworks (MOFs). Due to good properties such as high surface area, designable functionality, and uniform constitution, MOFs are regarded as promising electrocatalysts for the carbon dioxide electrochemical reduction reaction (eCO2RR). This review covers the importance, challenges, and mechanism of eCO2RR, and simply discusses the progress in the synthesis methods and characterization of MOFs. The review also thoroughly discusses the advances of single metal‐based MOFs, mixed metal‐based MOFs, and MOF derivatives as electrocatalysts for efficient eCO2RR.

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Section: Mof Derivatives For Eco 2 Rrmentioning

confidence: 99%

Metal‐Organic Frameworks for Efficient Electrochemical Reduction of Carbon Dioxide

et al. 2023

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“…The ECO 2 R is among options to overcome the energy crisis and ameliorate global warming, which is due to CO 2 emission. [ 1,2 ] It is projected that the pollution level in the atmosphere will increase by a factor of ≈25%. So, it is essential to address CO 2 emission through CO 2 sequestration, storage, and conversion.…”

Section: Introductionmentioning

confidence: 99%

Rational Design of Advanced Metal Organic Framework‐Based Nanostructured Catalysts toward Electrocatalytic CO₂ Conversion: A Mini Review

Alghamdi,

Al-Dolaimy,

Abdulrahman Althobaiti

et al. 2023

Energy Tech

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Carbon dioxide emission into the atmosphere, which originates from fossil fuels consumption, has led to a serious environmental and energy crisis. Electrochemical CO2 reduction reaction (CO2RR) into valuable chemicals such as carbon monoxide, ethanol, ethylene, and methane not only help lower the CO2 concentration in the atmosphere but is also beneficial for sustainable energy production. Therefore, numerous works are assigned to improving efficient electrocatalytic materials for the selective CO2RR. Metal–organic framework (MOF)‐derived catalytic materials mostly based on transition metals demonstrate permissible CO2RR owing to their specific composition, tunable surface nanostructure and texture, and affordable market prices. In this work, the best effort is put to describe the most basic concept of electrochemical CO2RR to provide a consensus. The effect of MOF structure and surface analysis are discussed. This is reason that MOFs as catalysts for electrochemical CO2RR offers several advantages over traditional catalysts, such as tunable surface structure, multifunctionality, selectivity control, and stability under CO2RR operation. And then, some of the most recent reported works on MOF‐based catalysts are summarized, to provide and inspire further investigations and ideas in this research field. However, despite these advantages, there are still research gaps that need to be addressed. Some of these gaps include being cost‐effective and economical process for preparing MOF‐based catalysts, long‐term stability for industrial usage, and scalability of the catalyst. Thereby, further studies are essential to fully exploit the potential of MOFs in advancing CO2RR technologies.

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Advancements in Ruthenium (Ru)‐Based Heterostructure Catalysts: Overcoming Bottlenecks in Catalysis for Hydrogen Evolution Reaction

Kuang,

Yang,

Feng

2024

Advanced Energy Materials

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Investigating clean and sustainable hydrogen generation from water splitting requires cost‐effective and highly efficient electrocatalysts for the hydrogen evolution reaction (HER). Ruthenium (Ru)‐based heterostructure catalysts have emerged as promising alternatives to precious Pt, offering significant potential to overcome current bottlenecks. Recent advancements in Ru‐based heterostructure catalysts have focused on achieving a balance between catalytic activity and stability. An overview of these developments provides insights into catalytic mechanisms and facilitates the development of novel catalysts. This review begins with an exploration of the enhanced activity of heterostructure catalysts, followed by a critical summary of synthetic strategies employed to fabricate these catalysts and their catalytic performances for HER. Attention is then directed to experimental endeavors aimed at enhancing the HER performance of Ru‐based heterostructure catalysts. Finally, the opportunities and challenges in developing heterostructure catalysts from the perspectives of material design and synthesis are discussed. Through these discussions, a comprehensive understanding of Ru‐based heterostructure catalysts and inspiring future research directions is the aim to provide.

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MOF-derived transition metal-based catalysts for the electrochemical reduction of CO₂to CO: a mini review

Abstract: The excessive emission of CO2 derived from the consumption of fossil fuels has caused severe energy and environmental crisis. The electrochemical reduction of CO2 into value-added products such as CO...

Cited by 18 publications

References 158 publications

Metal‐Organic Frameworks for Efficient Electrochemical Reduction of Carbon Dioxide

Metal‐Organic Frameworks for Efficient Electrochemical Reduction of Carbon Dioxide

Rational Design of Advanced Metal Organic Framework‐Based Nanostructured Catalysts toward Electrocatalytic CO₂ Conversion: A Mini Review

Advancements in Ruthenium (Ru)‐Based Heterostructure Catalysts: Overcoming Bottlenecks in Catalysis for Hydrogen Evolution Reaction

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MOF-derived transition metal-based catalysts for the electrochemical reduction of CO2to CO: a mini review

Abstract: The excessive emission of CO2 derived from the consumption of fossil fuels has caused severe energy and environmental crisis. The electrochemical reduction of CO2 into value-added products such as CO...

Cited by 18 publications

References 158 publications

Metal‐Organic Frameworks for Efficient Electrochemical Reduction of Carbon Dioxide

Metal‐Organic Frameworks for Efficient Electrochemical Reduction of Carbon Dioxide

Rational Design of Advanced Metal Organic Framework‐Based Nanostructured Catalysts toward Electrocatalytic CO2 Conversion: A Mini Review

Advancements in Ruthenium (Ru)‐Based Heterostructure Catalysts: Overcoming Bottlenecks in Catalysis for Hydrogen Evolution Reaction

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MOF-derived transition metal-based catalysts for the electrochemical reduction of CO₂to CO: a mini review

Rational Design of Advanced Metal Organic Framework‐Based Nanostructured Catalysts toward Electrocatalytic CO₂ Conversion: A Mini Review