The quantification of the bound and free water within spruce wood and the water and solid matrix interactions are still unknown by the researchers.Many specimens were firstly studied by Nuclear Magnetic Resonance function of the relative humidity. For each test, the bound and free water were calculated. After that, spruce wood specimens were studied by X-Ray Diffraction, function of the relative humidity. For each test, the crystalline and amorphous phases were quantified. This paper presents innovative results concerning the bound and free water uptake within wooden materials, and the water and wooden solid matrix interactions.