Molding of syndiotactic polystyrene under its melting temperature

Abstract

Syndiotactic polystyrene (SPS), a thermoplastic polymer that exhibits a high Tm in some crystalline forms, can be conveniently processed by a cold‐compaction technique. Processing temperatures in the range of 150–210°C, well below the Tm, gives rise to physicomechanical properties comparable and even better than those obtained by thermal compression or injection molding. The optimum treatment temperature seems to fall around 175°C. X‐ray diffraction analysis, thermal analysis, and density measurements suggest that such behavior is connected to phase transitions of SPS and favored by the presence of styrene included in the crystalline fraction. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 377–383, 2001