“…In fact, the softening or melting temperature of nanosize silica is expected to be much lower than that of bulk silica. 11 Furthermore, it was reported that CaCl 2 as a fluxing agent can lower the softening or melting temperature of silica. 12 Therefore, it is suggested that the network structure after immersion was formed through a partial softening or melting process of nano-SiO 2 in molten CaCl 2 at 900 1C.…”
Here we report Si nanowire growth by electrochemical reduction of nanometre silica in molten CaCl2; to our knowledge, this is the first report of an electrochemical route that provides crystalline Si nanowires in large quantities.
“…In fact, the softening or melting temperature of nanosize silica is expected to be much lower than that of bulk silica. 11 Furthermore, it was reported that CaCl 2 as a fluxing agent can lower the softening or melting temperature of silica. 12 Therefore, it is suggested that the network structure after immersion was formed through a partial softening or melting process of nano-SiO 2 in molten CaCl 2 at 900 1C.…”
Here we report Si nanowire growth by electrochemical reduction of nanometre silica in molten CaCl2; to our knowledge, this is the first report of an electrochemical route that provides crystalline Si nanowires in large quantities.
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