Molecular Engineering of Donor/π‐Bridge Enables High‐Efficiency and Long‐Lifetime Near‐Infrared TADF‐OLEDs
Yu Dai,
Jingyi Xu,
Xiongyan Lei
et al.
Abstract:The development of high‐efficiency near‐infrared (NIR) organic emitters has been severely constrained by strong and unavoidable non‐radiative decay governed by the “energy gap law”, which leads to low emission efficiencies and limited options for molecular design. Herein, comparative studies are performed on six‐ and five‐membered π‐bridge and a novel benzo[b]thiophene‐based donor is designed through elaborate molecular engineering, which outperforms widely‐used triphenylamine derivatives in constructing NIR t… Show more
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