Molecular hydration: Interfacial supersolidity and its functionality

Fang, Hengxin; Wang, Xuejie; Zhou, Yong; Zhang, Chenxu; Tan, Tingyuan; Yao, Chuang; Huang, Yongli; Wang, Biao; Sun, Chang Q

doi:10.1016/j.ccr.2023.215576

Coordination Chemistry Reviews

2024

DOI: 10.1016/j.ccr.2023.215576

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Molecular hydration: Interfacial supersolidity and its functionality

Hengxin Fang,

Xuejie Wang,

Yong Zhou

et al.

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Cited by 2 publications

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Coordination structure engineering of Cu-based electrocatalysts for electrocatalytic water splitting

Luo,

Liu,

Yang

et al. 2024

Coordination Chemistry Reviews

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Coordination structure engineering of Cu-based electrocatalysts for electrocatalytic water splitting

Luo,

Liu,

Yang

et al. 2024

Coordination Chemistry Reviews

View full text Add to dashboard Cite

Hydrogen Bond-Catalyzed Synthesis of Oxazolidinone over Ionic Liquid 1-Hydroxyethyl-3-methylimidazolium Acetate

Wu,

Guo,

Fang

et al. 2024

Ind. Eng. Chem. Res.

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Herein, we report a hydrogen bonding-catalyzed three-component reaction of 1,2-benzylamine, styrene oxide, and dimethyl carbonate over ionic liquid 1-hydroxyethyl-3-methylimidazolium acetate ([OH-EMIm][OAc]) to synthesize various oxazolidinones in excellent yields at 100 °C. This indicates that [OH-EMIm][OAc] can activate 1,2-benzylamine and styrene oxide through hydrogen bonding to form intermediate 2-(benzylamino)-1-phenylethan-1-ol, which further reacts with dimethyl carbonate activated by [OH-EMIm][OAc], producing oxazolidinone via intramolecular cyclization of the intermediate methyl benzyl-(hydroxy(phenyl)methyl)carbamate. Moreover, [OH-EMIm][OAc] could be reused five times without loss of activity. This protocol provides a facile and novel route to oxazolidinones, which may have promising application potential.

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Molecular hydration: Interfacial supersolidity and its functionality

Cited by 2 publications

References 186 publications

Coordination structure engineering of Cu-based electrocatalysts for electrocatalytic water splitting

Coordination structure engineering of Cu-based electrocatalysts for electrocatalytic water splitting

Hydrogen Bond-Catalyzed Synthesis of Oxazolidinone over Ionic Liquid 1-Hydroxyethyl-3-methylimidazolium Acetate

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