Molecular interaction for quasi-binary mixture of N-acyl amino sulfonate amphoteric surfactant from castor oil and stearyltrimethyl ammonium bromide

Li, Dan Ni; Zhang, Ye Xi; Ren, Zhao Hua; Cai, Le Le; Huang, Jing; Li, Bei Bei; Zhang, Qing; Yi, Meng Ting; Quan, Xiao Feng; Wang, Yunxiao; Wang, Ben Ru; Qian, Zheng Bo; Wang, Jun Ru; Tian, Huan; Yuan, Jie; Wang, Ni; Long, Qi Li; Zhang, Xuan Ming

doi:10.1016/j.molliq.2021.116813

Cited by 12 publications

(5 citation statements)

References 41 publications

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“…Thermodynamic characteristics demonstrate that the proposed method of micellization is enthalpically spontaneous. When amounts of AAS-CO were added to an aqueous solution, the free energy increased, favoring the formation of mixed micelle represented in Figure …”

Section: Computational Study Of Amino Acid–surfactant Interactionsmentioning

confidence: 99%

“…When amounts of AAS-CO were added to an aqueous solution, the free energy increased, favoring the formation of mixed micelle represented in Figure 10. 62 This work described the formation of a viscoelastic wormlike micellar system in a mixed non-ionic surfactant system. The anionic surfactant (LAD) was neutralized by 2,2′,2″-nitrilotriethanol (TEA) at various degrees of neutralization (1:1 via 1:1.5 to 1:2), and the influence of concentration and temperature was studied.…”

Section: Computational Study Of Amino Acid−surfactant Interactionsmentioning

confidence: 99%

“…When amounts of AAS-CO were added to an aqueous solution, the free energy increased, favoring the formation of mixed micelle represented in Figure 10 . 62 …”

Section: Computational Study Of Amino Acid–surfactant Interactionsmentioning

confidence: 99%

Section: Computational Study Of Amino Acid–surfactant Interactionsmentioning

confidence: 99%

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A Review on Interactions between Amino Acids and Surfactants as Well as Their Impact on Corrosion Inhibition

Muhammad

Singh

et al. 2022

ACS Omega

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Amino acid−surfactant interactions are central to numerous studies because of their increased effectiveness in chemical, biological, household and industrial use. This review will focus on the impact and effect of the physicochemical properties, temperature, pH, and surfactant chain length of the amino acid for detailed exploration of amino acids and surfactants in aqueous medium. The impact of cosolvent on self-aggregation, critical micelle concentration (CMC), and binding affinity with other biomolecules, as well as amino acid−surfactant interactions, are the epicenters. The results show that increasing the temperature causes negative enthalpy for ionic surfactants and micellization, implying that micellization and amino acids are thermodynamically spontaneous and exothermic, accompanied by positive entropy. As these physicochemical studies are additive, the amino acid and ionic surfactant interactions provide clues on protein unfolding and denaturation under different media, which further changes with a change in physiological conditions like pH, cosolvent, chain length, and temperature. On varying the pH, the net charge of the amino acid also changes and, subsequently, the binding efficiency of the amino acids to the surfactants. The presence of cosolvent causes a lowering in the hydrophobic chain, which changes the surfactant's CMC. At a reduced CMC, the hydrophobic characteristic of amino acid−surfactant associations is amplified, leading to rapid denaturation of proteins that act as propulsion under the influence of extended chain surfactants. Amino acids are one of the most intriguing classes of chemicals that produce high inhibitory efficacy. Amino acids are also a component of proteins and therefore, found in a significant part of the human body, further making them a promising candidate as corrosion inhibitors. In this review article, authors have also focused on the collection and investigation for application of amino acid−surfactant interactions in corrosion inhibition. Various predictive studies/in silico studies are also reported by many research groups, such as density functional theory (DFT) calculations and molecular dynamics simulations to obtain tentative electronic, structural, and physiochemical characteristics like energies of the highest occupied molecular orbitals and lowest unoccupied molecular orbitals, binding energy, Gibb's free energy, electronegativity, polarizability, and entropy. In silico studies are helpful for the mechanism predictions of the process occurring on metal surfaces.

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Section: Computational Study Of Amino Acid–surfactant Interactionsmentioning

confidence: 99%

Section: Computational Study Of Amino Acid−surfactant Interactionsmentioning

confidence: 99%

“…When amounts of AAS-CO were added to an aqueous solution, the free energy increased, favoring the formation of mixed micelle represented in Figure 10 . 62 …”

Section: Computational Study Of Amino Acid–surfactant Interactionsmentioning

confidence: 99%

Section: Computational Study Of Amino Acid–surfactant Interactionsmentioning

confidence: 99%

See 2 more Smart Citations

A Review on Interactions between Amino Acids and Surfactants as Well as Their Impact on Corrosion Inhibition

Muhammad

Singh

et al. 2022

ACS Omega

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“…Barai et al explored theoretical approaches to the synergistic interaction between hexadecyltrimethylammonium bromide (HTAB) and double‐headed anionic amino acid‐based surfactants (Barai et al, 2020). Ren et al probed the interaction behavior between an amphoteric sodium N ‐acyl amino sulfonate based on castor oil (AAS‐CO) and the cationic stearyltrimethyl ammonium bromide (STAB) (Li et al, 2021).…”

Section: Introductionmentioning

confidence: 99%

Interaction of saponification products of Robinia pseudoacacia seed oil with cetyltrimethyl ammonium bromide

Hou,

2023

J Surfact & Detergents

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The interaction between novel saponification products (RCOONa or RCOOK) of Robinia pseudoacacia seed oil and cetyltrimethyl ammonium bromide (CTAB) in aqueous solution have been investigated by surface tension method at 25°C. The critical micelle concentration (cmc) of RCOONa/CTAB and RCOOK/CTAB mixture were measured. The surface properties of saponification products, CTAB as well as the mixed system were explored and compared. The composition, activity coefficient of mixed micelle, and the interaction parameters (βσ, βM) between surfactants were estimated according to the Regular Solution Theory, the Clint's model and the Rubingh's model in the framework of pseudophase separation model. The experimental results suggested that both RCOONa and RCOOK have synergism with CTAB in mixed micelle formation and surface tension reduction through calculating of βσ and βM in the mixed system. This could be attributed to the strong interaction between the head groups with opposite charges in the surfactant molecules.

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Performance and mildness of alkyl glycoside hydroxypropyl sulfonate

Chang,

Jia

2024

J Surfact & Detergents

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Alkyl glycoside hydroxypropyl sulfonate (APGSHS), as a kind of anionic surfactant was successfully prepared using sodium 3‐chloro‐2‐hydroxypropane sulfonate and alkyl polyglucoside (APG). The surface and application properties of APGSHS were studied in detail. The results showed that APGSHS showed much enhanced solubility and there for better foaming and detergency properties than APG due to the introduction of sulfonate group. Then, the mildness of APGSHS and commercially available mild surfactants was compared using zein test and hemolysis of red blood cells (RBC) test. APGSHS has higher mildness than other surfactants, such as potassium lauroylglycinate (PLG), lauramidopropyl betaine (LAB), and sodium laurylmethyl taurate (LMT). The mechanism of mildness was investigated by studying the interaction between APGSHS and protein using zein model through micelle behavior and protein structure. It was observed that compared to other anionic surfactants such as sodium fatty alcohol polyoxyethylene ether sulfate (AES) and sodium dodecyl sulfate (SDS), APGSHS possesses a larger hydrophilic head group and causes less damage to the secondary structure of zein. Finally, the effect of different surfactants on the hair keratin loss during washing was evaluated. The results showed APGSHS had a minimal damaging effect on keratin in the hair, resulting in the lowest protein loss. This work suggests APGSHS as a promising ingredient for green and mild cleaning products.

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Molecular interaction for quasi-binary mixture of N-acyl amino sulfonate amphoteric surfactant from castor oil and stearyltrimethyl ammonium bromide

Cited by 12 publications

References 41 publications

A Review on Interactions between Amino Acids and Surfactants as Well as Their Impact on Corrosion Inhibition

A Review on Interactions between Amino Acids and Surfactants as Well as Their Impact on Corrosion Inhibition

Interaction of saponification products of Robinia pseudoacacia seed oil with cetyltrimethyl ammonium bromide

Performance and mildness of alkyl glycoside hydroxypropyl sulfonate

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