Molecular interaction of alcohols with acrylic esters in non-polar solvents

Abstract

The molecular interaction between alcohols (1-propanol, 1-pentanol, 1-heptanol, and 1-octanol) and acrylic esters (methyl methacrylate (MMA), ethyl methacrylate (EMA) and butyl methacrylate (BMA)) have been studied in carbon tetrachloride and benzene at 298 K using dielectric and FTIR spectroscopic methods. The result shows that, 1:1 complex is predominant in these systems. The strength of hydrogen bond (O-H:C=O) formation shows a significant dependence of on alkyl chain length of both alcohols and acrylic esters and the nature of the solvent used.

Hydrogen Bonding Interactions of m-Chlorotoluene with 1-Alkanol Analyzed by Thermodynamic, Fourier Transform Infrared Spectroscopy, Density Functional Theory, and Natural Bond Orbital

“…It is worth mentioning that the 1:1 complex is only a representation of possible interactions within the binary system. However, this assumption of the 1:1 complex is supported by previous studies on interactions of alkanols with different organic molecules such as alkylmethacrylates acrylic esters. , Full geometry optimization was carried out on each of the studied 1-alkanols and MCT. Geometry optimization was then carried out on MCT/1-alkanol complexes.…”

Molecular interactions of triethylamine and 1-dodecanol binary liquid mixtures

“…In other words, it quantifies the extent of polarization of the medium. Over many years, experimental results concerning the dielectric behaviour of binary solutions of polar-non polar mixtures have been published [1][2][3].These studies provide only the interaction among only one species.During the past few years, experimental results of polar-polar binary mixtures have been published [4][5][6][7]. Advanced microwave techniques have accelerated a remarkable development of measuring complex permittivity over a wide frequency range from 1 MHz to 20 GHz by a time domain reflectometry technique [8][9][10].…”