2021
DOI: 10.1021/acs.inorgchem.0c03425
|View full text |Cite
|
Sign up to set email alerts
|

Molecular Level Synthesis of InFeO3 and InFeO3/Fe2O3 Nanocomposites

Abstract: New heterometallic In−Fe alkoxides [InFe-(O t Bu) 4 (PyTFP) 2 ] (1), [InFe 2 (O neo Pen) 9 (Py)] (2), and [In-Fe 3 (O neo Pen) 12 ](3) were synthesized and structurally characterized. The arrangement of metal centers in mixed-metal framework was governed by the In:Fe ratio and the coordination preferences of Fe(III) and In(III) centers to be in tetrahedral and octahedral environments, respectively. 3 displayed a star-shaped socalled "Mitsubishi" motif with the central In atom coordinated with three tetrahedral… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2023
2023
2023
2023

Publication Types

Select...
2

Relationship

1
1

Authors

Journals

citations
Cited by 2 publications
(1 citation statement)
references
References 76 publications
0
1
0
Order By: Relevance
“…Thermogravimetric analysis (TG) of 1 (Figure 3a) indicated instant hydrolysis of the precursor in the initial phase which is common in metal alkoxides, which demonstrates their intrinsically high reactivity, making them attractive precursors for metal oxides. [30][31][32][33][34] The three-step decomposition led to a total mass loss of 69% (7.327 mg of 10.6189 mg) (Δm 1 = 64% (6.796 mg) in the range 25-260 °C, Δm 2 = 4% (0.425 mg) in the range 260-500 °C, and Δm 3 = 1% (0.106 mg) in the range 500-900 °C) that is close to the theoretical mass loss of 72% expected for the formation of MgFe 2 O 4 . The deviation in the weight loss is possible due to the initial hydrolysis, which is inevitable despite the precursor handling in dry nitrogen, of the sample.…”
Section: Resultsmentioning
confidence: 99%
“…Thermogravimetric analysis (TG) of 1 (Figure 3a) indicated instant hydrolysis of the precursor in the initial phase which is common in metal alkoxides, which demonstrates their intrinsically high reactivity, making them attractive precursors for metal oxides. [30][31][32][33][34] The three-step decomposition led to a total mass loss of 69% (7.327 mg of 10.6189 mg) (Δm 1 = 64% (6.796 mg) in the range 25-260 °C, Δm 2 = 4% (0.425 mg) in the range 260-500 °C, and Δm 3 = 1% (0.106 mg) in the range 500-900 °C) that is close to the theoretical mass loss of 72% expected for the formation of MgFe 2 O 4 . The deviation in the weight loss is possible due to the initial hydrolysis, which is inevitable despite the precursor handling in dry nitrogen, of the sample.…”
Section: Resultsmentioning
confidence: 99%