Molecular Modeling of Supercritical Processes and the Lattice—Gas Model
Yuri Konstantinovich Tovbin
Abstract:The existing possibilities for modeling the kinetics of supercritical processes at the molecular level are considered from the point of view that the Second Law of thermodynamics must be fulfilled. The only approach that ensures the fulfillment of the Second Law of thermodynamics is the molecular theory based on the discrete–continuous lattice gas model. Expressions for the rates of the elementary stage on its basis give a self-consistent description of the equilibrium states of the mixtures under consideratio… Show more
“…The thermodynamic background [15] of the gas-lattice model and its potential to describe processes at a supercritical state was reviewed by Tovbin [16]. Supercritical fluids possess applications as refrigerant fluids.…”
“…The thermodynamic background [15] of the gas-lattice model and its potential to describe processes at a supercritical state was reviewed by Tovbin [16]. Supercritical fluids possess applications as refrigerant fluids.…”
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