Molecular Orbital Engineering of Mixed-Addenda Polyoxometalates Boosts Light-Driven Hydrogen Evolution Activity

Chi, Manzhou; Zeng, Ying; Lang, Zhong-Ling; Li, Huijie; Xin, Xing; Dong, Yuanyuan; Fu, Fangyu; Yang, Guo-Yu; Lv, Hongjin

doi:10.1021/acscatal.4c00295

ACS Catal.

2024

DOI: 10.1021/acscatal.4c00295

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Molecular Orbital Engineering of Mixed-Addenda Polyoxometalates Boosts Light-Driven Hydrogen Evolution Activity

Manzhou Chi,

Ying Zeng,

Zhong-Ling Lang

et al.

Abstract: Inspired by the principle of molecular orbital engineering, two structurally well-defined polyoxometalate (POM)-based hydrogen-evolving catalysts, namely, [H 2 N-(CH 3 ) 2 ] 9.

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Cited by 4 publications

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Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate

Li,

Fu,

Zhao

et al. 2024

Chinese Chemical Letters

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Assembly of Y(III)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles

Yang,

Lin,

Zhang

et al. 2024

Chinese Chemical Letters

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Self-Assembled 8-Ti-Containing Polyoxomolybdate for the Photocatalytic Hydrogen Evolution

Wang,

Liu,

et al. 2024

Inorg. Chem.

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An S-shaped 8-Ti-containing polyoxomolybdate (NH 4 )-Cs 2 Na 6 H 3 [Ti 8 (GeMo 9 O 34 ) 2 (GeMo 5 O 23 ) 2 ]•44H 2 O (1) has been prepared under the one-pot hydrothermal method and further characterized. According to single-crystal X-ray, compound 1 consists of two {GeMo 9 O 34 } and two {GeMo 5 O 23 } segments, which are linked with a {Ti 8 O 34 } cluster. Moreover, the {GeMo 5 O 23 } fragment is rare and the first discovery, which enriches the lacunary Keggin-type family and offers the possibility of obtaining new structures. Among all of the reported polyoxomolybdates, compound 1 has the highest nuclearity of Ti centers. From the photocatalytic hydrogen evolution studies, compound 1 can be used as the heterogeneous catalyst with an H 2 evolution rate of 2392.6 μmol g −1 h −1 under minimally optimized conditions.

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Molecular Orbital Engineering of Mixed-Addenda Polyoxometalates Boosts Light-Driven Hydrogen Evolution Activity

Abstract: Inspired by the principle of molecular orbital engineering, two structurally well-defined polyoxometalate (POM)-based hydrogen-evolving catalysts, namely, [H 2 N-(CH 3 ) 2 ] 9.

Cited by 4 publications

References 56 publications

Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate

Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate

Assembly of Y(III)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles

Self-Assembled 8-Ti-Containing Polyoxomolybdate for the Photocatalytic Hydrogen Evolution

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