Molecular Recognition Directed Self-Assembly of Supramolecular Liquid Crystals

Percéc, Virgil; Heck, J.; Johansson, Gary; Tomazos, Dimitris; Kawasumi, Masaya; Chu, Peng-Cheng; Ungar, Goran

doi:10.1080/10587259408036075

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2023

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Cited by 33 publications

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“…In conclusion, a cross-linked polymer, prepared by the in situ polymerization of the liquid crystalline salt 1· (−)- 2 was found to work as a host with a flexible framework, of which the structural order was reversibly switched by changing the amount or shape of a guest incorporated in the polymer. The unique properties of the cross-linked polymers based on this concept, compared with conventional intercalation hosts, such as physical robustness, the kinetic stability, and size/shape tunability, would lead us to the further facile manipulation and more profound understanding of host−guest systems in the solid state.…”

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confidence: 99%

Switching of Structural Order in a Cross-Linked Polymer Triggered by the Desorption/Adsorption of Guest Molecules

et al. 2006

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A cross-linked polymer, prepared by the in situ polymerization of a thermotropic columnar liquid crystal, was found to work as a host with a flexible framework, which was reminiscent of intercalation hosts, such as clays, graphites, and coordination polymers. The structural order of the cross-linked polymer was reversibly switched by changing the amount or shape of a guest incorporated in the polymer.

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confidence: 99%