“…[1][2][3] Therefore, many approaches, such as rubbing, 4 stretching, 5 and friction-transfer, [6][7][8] have been developed to induce chain alignment in thin lms. An additional polymer layer, such as a rubbed polyimide lm 9 or a photo-induced azobenzene lm, has also been introduced into these approaches. 10,11 Most of these assisting thin layers are good insulators, whose thicknesses do not exceed tens of nanometers in the traditional PLED 5-layer structure.…”