Molecular simulation of [P8883][Tf2N] ionic liquid decorated silica in 6FDA-ODA based mixed matrix membrane for enhanced CO2/CH4 separation

Darban, Mehtab Ali; Lock, Serene Sow Mun; Ilyas, Suhaib Umer; Kang, Dun-Yen; Othman, Mohd Hafiz Dzarfan; Yiin, Chung Loong; Waqas, Sharjeel; Bashir, Zunara

doi:10.1039/d4ra02851a

RSC Adv.

2024

DOI: 10.1039/d4ra02851a

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Molecular simulation of [P8883][Tf₂N] ionic liquid decorated silica in 6FDA-ODA based mixed matrix membrane for enhanced CO₂/CH₄ separation

Mehtab Ali Darban,

Serene Sow Mun Lock,

Suhaib Umer Ilyas

et al.

Abstract: A computational molecular simulation approach to design hybrid membrane having [P8883][Tf2N] ionic liquid decorated silica as filler and 6FDA-ODA as the polymer for enhanced carbon dioxide separation from methane based on solution-diffusion mechanism.

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Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO₂ Capture: Progress, Challenges, and Prospects

Ali,

Mulk,

Khan

et al. 2024

Energy Fuels

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The rise in carbon dioxide (CO 2 ) emissions is a major driver of global warming, and climate change has intensified the focus on developing effective CO 2 capture technologies. Traditional methods, such as absorption, including amine-based systems, adsorption, and cryogenic separation, have been widely studied and implemented. However, many of these approaches face significant economic and environmental challenges, including high energy demands and operational inefficiencies. This highlights the need for more sustainable alternatives. Membrane-based CO 2 capture has emerged as a promising solution, offering benefits like reduced costs, compact design, and high operational efficiency. However, the main challenge in membrane development is achieving a defect-free polymer-inorganic interface that enhances separation performance without compromising permeability. The selection of a suitable filler material is crucial for optimizing the gas separation performance of these membranes. This review provides a comprehensive synthesis of the key principles involved in the preparation of mixed matrix membranes (MMMs), with a focus on the latest advancements in synthesis techniques, characterization methods, and surface modifications using cutting-edge polymers and filler materials. Beyond the fundamentals, it offers a critical analysis of the persistent challenges in MMM fabrication, integrating an in-depth techno-economic evaluation and sustainability assessment to position membrane technology in the context of industrial feasibility. The review also incorporates an up-to-date discussion on the technology readiness level (TRL) of membrane-based CO 2 capture research, a dimension often overlooked in existing literature. By identifying critical research gaps and outlining forward-looking perspectives, this work sets a foundation for accelerating innovation in the field.

show abstract

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO₂ Capture: Progress, Challenges, and Prospects

Ali,

Mulk,

Khan

et al. 2024

Energy Fuels

View full text Add to dashboard Cite

show abstract

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Molecular simulation of [P8883][Tf₂N] ionic liquid decorated silica in 6FDA-ODA based mixed matrix membrane for enhanced CO₂/CH₄ separation

Abstract: A computational molecular simulation approach to design hybrid membrane having [P8883][Tf2N] ionic liquid decorated silica as filler and 6FDA-ODA as the polymer for enhanced carbon dioxide separation from methane based on solution-diffusion mechanism.

Cited by 1 publication

References 143 publications

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO₂ Capture: Progress, Challenges, and Prospects

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO₂ Capture: Progress, Challenges, and Prospects

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Molecular simulation of [P8883][Tf2N] ionic liquid decorated silica in 6FDA-ODA based mixed matrix membrane for enhanced CO2/CH4 separation

Abstract: A computational molecular simulation approach to design hybrid membrane having [P8883][Tf2N] ionic liquid decorated silica as filler and 6FDA-ODA as the polymer for enhanced carbon dioxide separation from methane based on solution-diffusion mechanism.

Cited by 1 publication

References 143 publications

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO2 Capture: Progress, Challenges, and Prospects

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO2 Capture: Progress, Challenges, and Prospects

Contact Info

Product

Resources

About

Molecular simulation of [P8883][Tf₂N] ionic liquid decorated silica in 6FDA-ODA based mixed matrix membrane for enhanced CO₂/CH₄ separation

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO₂ Capture: Progress, Challenges, and Prospects

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO₂ Capture: Progress, Challenges, and Prospects