2008
DOI: 10.1111/j.1945-5100.2008.tb01115.x
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Molecular study of insoluble organic matter in Kainsaz CO3 carbonaceous chondrite: Comparison with CI and CM IOM

Abstract: Abstract-Kainsaz CO3 insoluble organic matter (IOM) was studied using Curie point pyrolysis, electronic paramagnetic resonance (EPR), and high-resolution transmission electron microscopy (HRTEM) to determine the effect of thermal metamorphism on molecular chondritic fingerprints. Pyrolysis released a very low amount of products that consist of one-and two-ring aromatic units with methyl, dimethyl, and ethyl substituents. Moreover, Kainsaz IOM contains two orders of magnitude fewer radicals than Orgueil, Murchi… Show more

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Cited by 23 publications
(29 citation statements)
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“…As shown by Raman spectrometry, the structural order of the carbonaceous matter increases with temperature [92,93]. There is a clear trend in losing the heteroelements, evidenced by a decrease in H/C, N/C and O/C elemental ratios, and in increasing the size of aromatic units [77,94]. Organic radicals seem to be more affected by thermal metamorphism than aqueous alteration.…”
Section: Diversity Among the Different Types Of Chondrites: Influencementioning
confidence: 87%
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“…As shown by Raman spectrometry, the structural order of the carbonaceous matter increases with temperature [92,93]. There is a clear trend in losing the heteroelements, evidenced by a decrease in H/C, N/C and O/C elemental ratios, and in increasing the size of aromatic units [77,94]. Organic radicals seem to be more affected by thermal metamorphism than aqueous alteration.…”
Section: Diversity Among the Different Types Of Chondrites: Influencementioning
confidence: 87%
“…Organic radicals seem to be more affected by thermal metamorphism than aqueous alteration. Indeed, in Kainsaz, a heated meteorite, the radical concentration is 2 orders of magnitude lower than in CI and CM, whereas organic radicals are abundant in Tagish Lake and Orgueil, which are often considered to be intensively altered [74,75,77].…”
Section: Diversity Among the Different Types Of Chondrites: Influencementioning
confidence: 99%
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“…As shown by Raman spectrometry, the structural order of the carbonaceous matter increases with temperature (Bonal et al 2006). There is also a clear trend in losing the heteroelements (evidenced by a decrease in H/C, N/C and O/C elemental ratios) a loss of aliphatic chains and in increasing the size of aromatic units (Remusat et al 2008). On the other hand, hydrothermal alteration may induce oxidation of some functional groups like O and S containing groups.…”
Section: Molecular Structure Of the Iom: A Peculiar Macromoleculementioning
confidence: 88%
“…As shown by Raman spectrometry, the structural order of the carbonaceous matter increases with temperature [14]. There is a clear trend in losing the heteroelements, evidenced by a decrease in H/C, N/C and O/C elemental ratios, a loss of aliphatic chains and in increasing the size of aromatic units [41,42]. On the other hand, hydrothermal alteration may induce oxidation of some functional groups like O and S containing groups.…”
Section: The Insoluble Organic Mattermentioning
confidence: 95%