Molecularly imprinted polymers based on methacrylic acid and ethyleneglycol dimethacrylate for l-lysine recognition

Писарев, О. А.; Polyakova, I. V.

doi:10.1016/j.reactfunctpolym.2018.06.002

Cited by 20 publications

(9 citation statements)

References 28 publications

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“…The equilibrium data were fitted with both Langmuir and Freundlich models (Fig 9 and Table 2). Compared with the Freundlich model, the Langmuir model fitted well to the adsorption of chromate on MA-1 and MA-10, suggesting that MA-1 and MA-10 had an energetically homogeneous surface for chromate adsorption [28]. The maximum adsorption capacity (q m ) of MA-10 was 183.2 mg/g, which was lower than 222.2 mg/g on magnetic graphene oxide [29], but was higher than 51.8 mg/g on jacobsite/chitosan nanocomposites [30], 153.9 mg/g on magnetic chitosan particles [31], and 169.5 mg/g on polypyrrole/Fe 3 O 4 nanocomposite [32] ( Table 3).…”

Section: Plos Onementioning

confidence: 95%

Upcycling of groundwater treatment sludge to magnetic Fe/Mn-bearing nanorod for chromate adsorption from wastewater treatment

Dong

Chen

et al. 2020

PLoS ONE

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Groundwater treatment sludge is a Fe/Mn-bearing waste that is mass produced in groundwater treatment plant. In this study, sludge was converted to a magnetic adsorbent (MA) by adding ascorbate. The sludge was weakly magnetised in the amorphous form with Fe and Mn contents of 28.8% and 8.1%, respectively. After hydrothermal treatment, Fe/Mn oxides in the sludge was recrystallised to siderite and rhodochrosite, with jacobsite as the intermediate in the presence of ascorbate. With an increment in ascorbate dosage, the obtained magnetic adsorbent had a significant increase in chromate adsorption but a decrease in magnetisation. When the M ascorbate /M Fe molar ratio was 10, the produced MA-10 was a dumbbell-shaped nanorod with a length of 2-5 μm and a diameter of 0.5-1 μm. This MA-10 showed 183.2 mg/g of chromate adsorption capacity and 2.81 emu/g of magnetisation. The mechanism of chromate adsorption was surface coprecipitation of the generated Cr 3+ and Fe 3+ /Mn 4+ from redox reaction between chromate and siderite/rhodochrosite on MA-10, separately. This study demonstrated an efficient recycling route of waste sludge from groundwater treatment to produce MA for treating chromate-bearing wastewater.

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Section: Plos Onementioning

confidence: 95%

Upcycling of groundwater treatment sludge to magnetic Fe/Mn-bearing nanorod for chromate adsorption from wastewater treatment

Dong

Chen

et al. 2020

PLoS ONE

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“…where m-the mass of the obtained polymer (g); and m theor -the theoretical mass of the polymer (g). The bulk density, ρ bulk (g/cm 3 ), of synthesized polymers in the solvated state was determined by the gravimetric method by weighing 1 cm 3 of the sorbent on an analytical balance, previously swollen in n-propyl alcohol (the alcohol was separated by centrifugation) [44]. This value includes the true density of sorbents, voids in the sorbent (porosity), and the space between particles.…”

Section: Physicochemical Properties Of Polymersmentioning

confidence: 99%

The Effect of the Synthesis Method on Physicochemical Properties of Selective Granular Polymer Sorbents

Osipenko

Garkushina

2022

Polymers

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Investigation of the effect of the polymer synthesis method on physicochemical properties of sorbents is one of the topical problems in the chemistry of macromolecular compounds that has high scientific and practical interest. Determination of the optimal synthesis method will make it possible to create sorbents with physicochemical properties that led to the realization of effective sorption. In this work, we investigated the effect of synthesis methods (Pickering emulsion polymerization and precipitation polymerization in solution) of granular polymers based on 2-hydroxyethyl methacrylate and ethylene glycol dimethacrylate on physicochemical and sorption properties. The synthesis by Pickering emulsion polymerization led to improvement of the n-propyl alcohol diffusion into the polymer network and to the formation of more homogeneous and structurally stable polymer networks. Creating selective polymer networks by Pickering emulsion polymerization compared to precipitation polymerization in solution led to an increase in porosity, creation of more segregated surface of granules, improvement of binding sites availability at the temperature of 37 °C, and formation of the homogeneous sorption surface with high affinity to target molecules at 25 °C and 37 °C. Selective polymers synthesized by both polymerization methods had the largest values of available sorption surfaces areas for target molecules at 37 °C.

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“…The most recent developments comprised the adaptation of this type of CSP to monoliths, nanoparticles, and predominantly to polymers. The introduction of different supports such as alginate microspheres [ 254 ] or polymer functionalized with quantum dots [ 255 ] were also reported as well as the description of different functional monomers and crosslinking agents [ 256 , 257 , 258 , 259 ].…”

Section: Chiral Stationary Phases: Recent Developmentsmentioning

confidence: 99%

Chiral Stationary Phases for Liquid Chromatography: Recent Developments

et al. 2019

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The planning and development of new chiral stationary phases (CSPs) for liquid chromatography (LC) are considered as continuous and evolutionary issues since the introduction of the first CSP in 1938. The main objectives of the development strategies were to attempt the improvement of the chromatographic enantioresolution performance of the CSPs as well as enlarge their versatility and range of applications. Additionally, the transition to ultra-high-performance LC were underscored. The most recent strategies have comprised the introduction of new chiral selectors, the use of new materials as chromatographic supports or the reduction of its particle size, and the application of different synthetic approaches for preparation of CSPs. This review gathered the most recent developments associated to the different types of CSPs providing an overview of the relevant advances that are arising on LC.

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Molecularly imprinted polymers based on methacrylic acid and ethyleneglycol dimethacrylate for l-lysine recognition

Cited by 20 publications

References 28 publications

Upcycling of groundwater treatment sludge to magnetic Fe/Mn-bearing nanorod for chromate adsorption from wastewater treatment

Upcycling of groundwater treatment sludge to magnetic Fe/Mn-bearing nanorod for chromate adsorption from wastewater treatment

The Effect of the Synthesis Method on Physicochemical Properties of Selective Granular Polymer Sorbents

Chiral Stationary Phases for Liquid Chromatography: Recent Developments

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