Molecule self-assembly on alumina ceramic insulator to enhance its vacuum surface voltage withstand strength

Abstract

Molecule self-assembly on the surface of alumina ceramic and its influence on the surface flashover characteristics of the alumina ceramic insulators were studied in this paper. First, octadecyltrichlorosilane was assembled on the surface of alumina ceramic insulators in the toluene solution. Then, 393 K thermal treatment of 2 h was conducted on the specimens to promote the growth of the molecule membrane. Quality detection of the prepared molecule membrane by Energy Dispersive x-ray Analysis and water contact angle test showed that the molecules were linked to the alumina surface and the arrangement of the molecules on the surface was regular and tight. Gas release characteristic suggested that the formation of the molecule membrane made the gas release rate of the treated alumina decrease. The flashover voltage test on the home-made, short-pulsed, high-voltage vacuum platform indicated that the flashover voltages of the treated insulators increased by over 200% compared with the original alumina insulators. These results indicated that a layer of regular molecule membrane was formed on the surface of alumina through molecule self-assembly, which could improve the surface voltage withstand strength of the treated insulators.

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