the 3.94 obtained for the ethyl acetate-water system, considering the accuracy of the measurements, that rounding them all off to 3.9 seems most reasonable:( 3 ) Figure 9 shows the comparison of the new data as well as the earlier data (11) from baffled vessels with those computed from Equation ( 3 ) . I t is not now possible to recover the information needed to include the earlier data from unbaffled vessels, unfortunately. Most of the data are represented by Equation ( 3 ) within 20%. Considering the great number of measurements represented by each plotted point, the scatter is not considered excessive, and the applicability of the proposed mechanism seems reasonably well confirmed. More reliable coalescence data are obviously urgently needed. Chemical reactors utilizing downward flowing liquid films have certain advantages when the reaction temperature must be carefully controlled ( 1 ) . When the reaction is highly exothermic, the wall is cooled and the film is kept thin. Generally, the gas-phase reactant is diluted, and the flows are concurrent to avoid flooding. Chien (2) has correlated the static pressure gradient and superficial friction factor with the superficial gas and liquid Reynolds numbers. Stainthorp and Batt (21 ) have investigated the wave properties in a downward concurrent two-phase system. Although many investigations have been performed with falling films (for example see references 4 to 6 ) , much less Correspondence concerning this article should be addressed to Prof.F. H. Shair.
Page 920July, 1971is known about the flow within thin liquid films which are influenced by shear at the gas-liquid interface and by heat transfer. In order to predict the behavior of a chemical reactor, a residence time distribution function must be known ( 7 , 8 ) . Tracer studies are often used to determine the validity of a fluid mechanical model. For reasons of economy these studies usually involve the rapid injection of a small amount of tracer at the reactor entrance, and monitoring the fluid at the reactor exit, Since the F diagram, the internal age distribution function, and the exit age distribution function are interrelated in a simple manner, knowledge of any one function allows the determination of the other two functions. As pointed out by Danckwerts ( 7 ) , the F diagram (or F function) is easy to obtain, and permits certain calculations to be made concerning thc performance of the system when used, for instance, as a Consequently, the solution to the problem under consideration will be presented in terms of the F diagram 01 F function. It is noted that the F function is simply that integral of the exit age distribution function E .G. I. Taylor (9) established the analytical foundation concerning the treatment of dispersion in which both convcction and diffusion are important. Although several significant extensions have been made to the theory of such dispersions (10 to 1 3 ) , the laminar Newtonian flow in a film when influenced by both heat transfer and interfacial shear has not been available pr...