Monitoring of some trace metals in honeys by flame atomic absorption spectrometry after ultrasound assisted-dispersive liquid liquid microextraction using natural deep eutectic solvent

Altunay, Nail; Elık, Adıl; Gürkan, Ramazan

doi:10.1016/j.microc.2019.03.003

Cited by 87 publications

(26 citation statements)

References 44 publications

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“…Food consumption is de ned as the main pathway for humans to be exposed to pollutants (Khillare et al 2012). Rapidly increasing industrialization causes adverse effects on the ecosystem and the environment, which leads to food pollution (Altunay et al, 2019). Foods contaminated with POPs are present a high probability of posing a potential health risk for the consumers (Rusin et al 2019).…”

Section: Health Risk Assessment Of Pahs and Pcbsmentioning

confidence: 99%

“…In parallel with the increase in population, the demand for basic food products is increasing day by day (Ruby et al 2019). However, rapidly increasing industrialization causes deterioration in the environment and ecosystem, leading to pollution of basic food products (Altunay et al, 2019). It is essential to monitor pollutants in basic food products such as honey and pollen to prevent health risks that may occur due to human consumption of food (Panseri et al 2020).…”

Section: Introductionmentioning

confidence: 99%

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Concentration levels and an assessment of human health risk of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in honey and pollen

Sari

Esen

2022

Preprint

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Persistent organic pollutants (POPs) such as polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) accumulate in the food chain due to their physical and chemical properties and adversely affect human health. For this reason, this study aimed to determine the PAH and PCB concentration levels in pollen and honey samples in urban and semi-urban areas and to evaluate the risk of cancer that may occur by ingestion in Bursa, Turkey. The average total concentrations of 14 PAH (∑14PAH) compounds in pollen and honey samples were found to be 304.3±192.3 ng/g (average±standard deviation) and 650.2±118.1 ng/g for the urban area, and 329.6±160.6 ng/g and 464.3±66.4 ng/g for the semi-urban area, respectively. Similarly, ∑14PCB concentrations in pollen and honey samples were found to be 8.7±3.6 ng/g and 13.0±4.8 ng/g for the urban area, and 7.7±2.2 ng/g and 17.4±4.0 ng/g for the semi-urban area, respectively. It was determined that the pollen and honey samples in both sampling areas were affected by local PCB sources. Finally, while there was no cancer risk for PCBs due to ingestion of honey and pollen in both sampling areas, acceptable cancer risk has been calculated for PAHs.

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Section: Health Risk Assessment Of Pahs and Pcbsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Concentration levels and an assessment of human health risk of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in honey and pollen

Sari

Esen

2022

Preprint

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“…In 2019, Altunay et al [62] employed for the first time a DESs synthesized by 'natural' components, termed as 'natural DES' (NADES) [63], for a DLLME application. In this work, citric acid and sucrose were used in order to extract some metals from honey.…”

Section: Deep Eutectic Solventsmentioning

confidence: 99%

Use of green alternative solvents in dispersive liquid‐liquid microextraction: A review

Grau

Azorín

Benedé

et al. 2021

J of Separation Science

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Dispersive liquid-liquid microextraction is one of the most widely used microextraction techniques currently in the Analytical Chemistry field, mainly due to its simplicity and rapidity. The operational mode of this approach has been constantly changing since its introduction, adapting to new trends and applications.Most of these changes are related to the nature of the solvent employed for the microextraction. From the classical halogenated solvents (e.g., chloroform or dichloromethane), different alternatives have been proposed in order to obtain safer and non-pollutants microextraction applications. In this sense, low density solvents, such as alkanols, switchable hydrophobicity solvents and ionic liquids were the first and most popular replacements for halogenated solvents, which provided similar or better results than these classical dispersive liquid-liquid microextraction solvents.However, despite the good performances obtained with low density solvents and

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“…Several conditions, such as the volume of the NADES, the type and volume of aprotic solvent to obtain a cloudy state, ultrasound time and temperature, sample volume, etc., had to be optimized before any application. The limits of detection and quantification were in the range of 0.23–0.87 μg/kg and 0.78–2.94 μg/kg for the analytes, respectively, and a range of 90.3–98.4% for the recovery [ 109 ].…”

Section: Microextraction Techniques Using Desmentioning

confidence: 99%

Microextraction Techniques with Deep Eutectic Solvents

2020

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In this review, the ever-increasing use of deep eutectic solvents (DES) in microextraction techniques will be discussed, focusing on the reasons needed to replace conventional extraction techniques with greener approaches that follow the principles of green analytical chemistry. The properties of DES will be discussed, pinpointing their exceptional performance and analytical parameters, justifying their current extensive scientific interest. Finally, a variety of applications for commonly used microextraction techniques will be reported.

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Monitoring of some trace metals in honeys by flame atomic absorption spectrometry after ultrasound assisted-dispersive liquid liquid microextraction using natural deep eutectic solvent

Cited by 87 publications

References 44 publications

Concentration levels and an assessment of human health risk of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in honey and pollen

Concentration levels and an assessment of human health risk of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in honey and pollen

Use of green alternative solvents in dispersive liquid‐liquid microextraction: A review

Microextraction Techniques with Deep Eutectic Solvents

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