“…188 A synthesis has been devised for the hitherto unobtainable [Sm{N(SiMe 3 ) 2 }(cot)] n and its adduct [Sm{N(SiMe 3 ) 2 }(thf)(cot)]. 189 4 Actinides…”
“…188 A synthesis has been devised for the hitherto unobtainable [Sm{N(SiMe 3 ) 2 }(cot)] n and its adduct [Sm{N(SiMe 3 ) 2 }(thf)(cot)]. 189 4 Actinides…”
Monomeric cyclooctatetraenyl rare-earth metal complexes (COT)LnI(thf) 3 were examined by X-ray structure analysis for Ln = La and Sm being isostructural to the Nd and Ce congeners. Reaction of the lanthanum derivative with excess
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