2022
DOI: 10.1021/acsenergylett.2c01556
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Monolithic Perovskite–Perovskite–Silicon Triple-Junction Tandem Solar Cell with an Efficiency of over 20%

Abstract: Here we report a monolithic perovskite–perovskite–silicon triple-junction tandem solar cell with an efficiency of over 20%, an open-circuit voltage of 2.74 V, and a fill factor of 86%, which are the highest values for double- or triple-junction perovskite-based tandems reported to date. The concept and design presented here are an important milestone toward low-cost triple-junction tandem photovoltaics.

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Cited by 43 publications
(40 citation statements)
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“…Using this strategy, the authors fabricated all-perovskitetandem solar cells with a certified PCE of 26.4% that maintained over 90% of the initial PCE after 600 h under illumination at the maximum power point in an ambient environment. It is worth mentioning that a monolithic perovskite-perovskite-silicon based triple-junction tandem solar cell with an efficiency of over 20%, a V oc of 2.74 V, and a FF of 86% was recently demonstrated 39 . However, to compensate for the increased cost of such a complicated device structure, the PCEs would need to increase further.…”
Section: Tandem Solar Cellsmentioning
confidence: 99%
“…Using this strategy, the authors fabricated all-perovskitetandem solar cells with a certified PCE of 26.4% that maintained over 90% of the initial PCE after 600 h under illumination at the maximum power point in an ambient environment. It is worth mentioning that a monolithic perovskite-perovskite-silicon based triple-junction tandem solar cell with an efficiency of over 20%, a V oc of 2.74 V, and a FF of 86% was recently demonstrated 39 . However, to compensate for the increased cost of such a complicated device structure, the PCEs would need to increase further.…”
Section: Tandem Solar Cellsmentioning
confidence: 99%
“…The triple junction cells show no significant progress in terms of device performance during the last year. For Si/perov/perov and all‐perovskite devices, the top efficiencies are still 20.1% [ 38 ] and 19.9%, [ 39 ] which are significantly smaller in comparison with most of the perovskite‐based single and double junction devices. On the other hand, the latest record of GaInP/GaAs/GaInAs photovoltaic cell with a 39.5% efficiency reported by France et al.…”
Section: Highest Efficiency Research Photovoltaic Cellsmentioning
confidence: 99%
“…3c, J-V curves of various halide perovskite tandem solar cells with benchmarked power conversion efficiencies were compared. 46,[52][53][54][55][56] Through more sophisticated band gap control of subcell materials and multilayer interface engineering, the PCE for each type of halide perovskite tandem solar cell has been continuously increased. As the number of subcells constituting the tandem solar cell increases, the open circuit voltage (V oc ) increases, and the short circuit current density ( J sc ) decreases since the photovoltage is merged and the current density converges to the lower value.…”
Section: Halide Perovskite Photovoltaicsmentioning
confidence: 99%