“…The complexes all have two absorption peaks at 197 and 247 nm, which represent the conjugated π–π* transition of the aromatic ring and the n–π* transition of the viologen functional group, respectively. 32,33 Single emission peaks at 504, 544 and 532 nm are presented by complexes 1–3 , respectively, when excited at 325 nm (Fig. 2a).…”
Complexes 1–3 exhibited excellent pH sensing and Hg2+ sensing capabilities in both methanol and PBS buffer solutions. The interaction between Br−, the thiophene S atoms and Hg2+ in complexes 2–3, resulted in a distinctive dual-signal mode.
“…The complexes all have two absorption peaks at 197 and 247 nm, which represent the conjugated π–π* transition of the aromatic ring and the n–π* transition of the viologen functional group, respectively. 32,33 Single emission peaks at 504, 544 and 532 nm are presented by complexes 1–3 , respectively, when excited at 325 nm (Fig. 2a).…”
Complexes 1–3 exhibited excellent pH sensing and Hg2+ sensing capabilities in both methanol and PBS buffer solutions. The interaction between Br−, the thiophene S atoms and Hg2+ in complexes 2–3, resulted in a distinctive dual-signal mode.
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