2018
DOI: 10.3390/magnetochemistry4040045
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Mononuclear Lanthanide(III)-Salicylideneaniline Complexes: Synthetic, Structural, Spectroscopic, and Magnetic Studies

Abstract: The reactions of hydrated lanthanide(III) [Ln(III)] nitrates and salicylideneaniline (salanH) have provided access to two families of mononuclear complexes depending on the reaction solvent used. In MeCN, the products are [Ln(NO3)3(salanH)2(H2O)]·MeCN, and, in MeOH, the products are [Ln(NO3)3(salanH)2(MeOH)]·(salanH). The complexes within each family are proven to be isomorphous. The structures of complexes [Ln(NO3)3(salanH)2(H2O)]·MeCN (Ln = Eu, 4·MeCN_Eu, Ln = Dy, 7·MeCN_Dy; Ln = Yb, 10·MeCN_Yb) and [Ln(NO3)… Show more

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Cited by 14 publications
(15 citation statements)
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“…Consequently, only some doubt could remain about the nature of the solvent molecule coordinated to the gadolinium(III) ion, which could be methanol or water, as proposed in (Scheme 2). A similar coincidence between cell parameters exist for the already mentioned isostructural compounds [Ln(H 3 L )(NO 3 )(H 2 O)](NO 3 ) 2 •complexes (Ln = Gd, Tb, Dy, Er) [16], and for other isostructural series even with different solvated molecules [48].…”
Section: Synthetic Methodssupporting
confidence: 81%
“…Consequently, only some doubt could remain about the nature of the solvent molecule coordinated to the gadolinium(III) ion, which could be methanol or water, as proposed in (Scheme 2). A similar coincidence between cell parameters exist for the already mentioned isostructural compounds [Ln(H 3 L )(NO 3 )(H 2 O)](NO 3 ) 2 •complexes (Ln = Gd, Tb, Dy, Er) [16], and for other isostructural series even with different solvated molecules [48].…”
Section: Synthetic Methodssupporting
confidence: 81%
“…The absence of bands that would be indicative of the monodentate and bidentate coordinated nitrato groups (present in the structure of the cluster) is rather surprising. This suggests [29,30] that the nitrato ligands are replaced by bromides that are in excess in the KBr matrix, thus producing ionic nitrates (KNO 3 ); this replacement is facilitated by the pressure that is applied for the preparation of the KBr matrix. As expected, extra nitrato bands appear in the mull (nujol, hexachlorobutadiene) spectra of 2.…”
Section: Spectroscopic Characterization In Briefmentioning
confidence: 99%
“…As expected, extra nitrato bands appear in the mull (nujol, hexachlorobutadiene) spectra of 2. For example, the bands at 1501 and 1300 cm −1 are assigned [28][29][30]…”
Section: Spectroscopic Characterization In Briefmentioning
confidence: 99%
“…For a given bond, the Ln-O/N bond lengths follow the Nd>Dy order ( Table 1 ) due to lanthanide contraction; this trend is also observed for the Ln III… Ln III distances. The Ln-O/N bond lengths in 1 and 5 are typical for 9-coordinate Nd(III) [ 33 , 56 , 57 ] and Dy(III) [ 35 , 38 , 41 , 54 , 58 , 59 , 60 , 61 , 62 ]. The Ln1/Ln1′ coordination geometry was evaluated using the program SHAPE [ 61 , 63 ] and is best described as muffin-type ( Figure S1, Table S2 ); an alternative description of the polyhedron could be that of a spherical-capped square antiprism.…”
Section: Resultsmentioning
confidence: 99%
“…Ln III distances. The Ln-O/N bond lengths in 1 and 5 are typical for 9-coordinate Nd(III) [33,56,57] and Dy(III) [35,38,41,54,[58][59][60][61][62]. The Ln1/Ln1 coordination geometry was evaluated using the program SHAPE [61,63] and is best described as muffin-type (Figure S1, Table S2); an alternative description of the polyhedron could be that of a spherical-capped square antiprism.…”
Section: Characterization Of Selected Complexesmentioning
confidence: 99%