This study examines the interaction of Mg(II) and Ca(II) with morin (2 0 ,3,4 0 ,5,7-pentahydroxyflavone) in conjunction with the appraisal of antioxidant and biological properties of the complexes. The complexes were characterized by UV-Vis spectroscopy, FT-IR, 1 H NMR, 13 C NMR, thermal, and elemental analyses. The complexes have also been studied to determine metal : ligand stoichiometry. For antioxidant studies, it may be induced that complex formation increases the scavenging ability because of the differential and selective role of metals in free radical scavenging. The bioactivity studies show that both complexes have remarkable antibacterial properties against Micrococcus flavus and Staphylococcus aureus.