“…So far, many fabrication strategies to prepare silver NPs have been built, including photoreduction [27], microemulsion [28], biochemistry [29], solvothermal reaction [16], template strategy [30], electrochemical deposition [31], bionic technology [32], seeding growth approach [33], and micro-wave [34] [35] assisted reduction. Among all these synthesis methods, due to the ability to accurately design and engineer structures on nanometer scale, hydrothermal method have been proved to be a fascinating choice for selecting geometric variables (e.g., size and shape) and tailoring the optical properties of silver NPs to boost the SERS signals in a predictable way [36].…”