Electrodeposited Ni-W alloy coating is considered as one of the most suitable candidate to replace the environmentally hazardous hexavalent hard chromium coatings. However, it is necessary to carry out heat-treatment at a high temperature to improve its microhardness and refine its grain. In the present work, an alternative high frequency induction heat-treatment (HFI-HT) technology was used to improve surface microhardness of Ni-W/SiC composite coatings, which were electrodeposited from an ammonium-citrate bath, containing suspended green SiC particles. Transformation of amorphous to crystalline structure can be observed after HFI-HT. The precipitation of a Ni 6 W 6 C phase rather than a Ni 4 W phase occurs by prolonging induction time to 64 s at a power density of 21 W mm −2 or turning power density up to 42 W mm −2 for 4 s. While the two phases of Ni 6 W 6 C and Ni 4 W can be precipitated at 900°C. The microhardness of Ni-W/SiC composite coatings can be improved up to 1100 HV with HFI-HT at 21 W mm −2 for 8 s, which is comparable to that of hard chrome coatings.