39The effect of individual and combined addition of both nanosilica (NS) and 40 polycarboxylate-ether plasticizer (PCE) admixtures on aerial lime mortars was studied. 41The sole incorporation of NS increased the water demand, as proved by the mini-spread 42 flow test. An interaction between NS and hydrated lime particles was observed in fresh 43 mixtures by means of particle size distribution studies, zeta potential measurements and 44 optical microscopy, giving rise to agglomerates. On the other hand, the addition of PCE 45 to a lime mortar increased the flowability and accelerated the setting process. PCE was 46shown to act in lime media as a deflocculating agent, reducing the particle size of the 47 agglomerates through a steric hindrance mechanism. Mechanical strengths were 48 improved in the presence of either NS or PCE, the optimum being attained in the 49 combined presence of both admixtures that involved relevant microstructural 50 modifications, as proved by pore size distributions and SEM observations. 51 the technical characteristics of the final product and/or addressing environmental issues 58 [3][4][5]. The addition of nanosilica (NS) has attracted increasing interest because of the 59 filling effect, which improves the particle size distribution, thus reducing porosity, and 60 the pozzolanic reaction between NS and calcium hydroxide (CH) yielding calcium 61 silicate hydrates (C-S-H). These actions result in enhanced mechanical strength [6][7][8]. 62The filling of the interparticle space leads to a denser packing and reduces the water 63 demand, as there is no need to fill the space with water. In this case, the use of a 64 superplasticizer is required in order to guarantee workability [9]. Furthermore, the 65 strong tendency of NS to agglomerate also may make it necessary to use a dispersing 66 additive in order to overcome this problem and to ensure enough reactive surface for the 67 filling effect and C-S-H formation [7,10,11]. Dispersing additives are the so-called 68 plasticizers or superplasticizers, which have a water reducing action on cement 69 materials. When superplasticizers are added, workability at a constant water/cement 70 ratio is improved. Alternatively, the same workability as that of plain cement paste can 71 be reached with an outstanding reduction in water content. In the latter case, cement 72 materials with higher mechanical strengths can be obtained. The adsorption of the 73 plasticizer molecules on the solid particles, either by modifying the surface charge (zeta 74 potential) of the particles, thus increasing the electrostatic repulsion, or by steric 75 hindrance, causes a dispersing action, which has been claimed to be responsible for the 76 increase in fluidity of the cement paste [12]. The interaction between the 77 superplasticizer and the particles of the binder could be affected by the presence of 78 4 mineral additions (such as NS, silica fume or fly ash), which means that the 79 compatibility between them needs to be studied [13]. 80
81The interest in usi...