“…The C 1s spectra with high resolution were resolved into three distinct peaks at 284.2, 284.6, and 287.1 eV, which correspond to the presence of CC, C–O, and CO bonds, respectively (Figure S5a). − In Figure S5b, the Co 2p 1/2 and Co 2p 3/2 peaks of Ir@Co-BPDC were observed at energy levels of 781.5 and 797.7 eV, respectively, accompanied by two satellite peaks at energies of 785.7 and 803.7 eV, which exhibited a pattern similar to that of Co 2+ . , The main peak for Co 2p 3/2 in Figure S5b appears at approximately 781.7 eV, which typically corresponds to a Co(II) state. Co(II) would exhibit the 2p 3/2 peak within a binding energy range of approximately 780–785 eV, while Co(III) would be positioned at a higher binding energy. , We observe that the binding energy for the sample is slightly higher than the standard peak for Co(II), possibly due to the influence of the ligand field.…”