Mössbauer experiments on bismuth-antimony alloys

The Subtle Influence of Binary versus Homoatomic Zintl Ions: The Phenyl‐Ligated Trimetallic Cage [Sn2Sb5(ZnPh)2]3−

“…Similar shifts have been reported for elemental antimony (À11.6 mm s À1 ) and SnSb (À10.5 mm s À1 ). [37][38][39] For compound 3, the corresponding signals were also observed in both 119 Sn and 121 Sb Mçssbauer experiments, which confirm, in spite of lower resolution, the mixed Sn/Sb situation in the seven-atom cage (see the Supporting Information).…”

Impact behavior of unidirectional polyethylene–glass fibers: Resol/vinyl acetate‐2‐ethylhexylacrylate interpenetrating polymer network systems

“…Compound 1 falls into the range for Sb 0 compounds, in agreement with the Zintl–Klemm concept for the [Sn 2 Sb 2 ] 2− anion. Similar shifts have been reported for elemental antimony (−11.6 mm s −1 ) and SnSb (−10.5 mm s −1 ) 37–39. For compound 3 , the corresponding signals were also observed in both 119 Sn and 121 Sb Mössbauer experiments, which confirm, in spite of lower resolution, the mixed Sn/Sb situation in the seven‐atom cage (see the Supporting Information).…”

Antimony-121 Mössbauer Spectral Study of the Eu14MnSb11 and Yb14MnSb11 Zintl Compounds

“…AlSb has an isomer shift of −7.8 mm/s, an isomer shift that corresponds to an electronic configuration 5s 1.75 5p 3.44 for antimony and a valence electron density at the nucleus of 85.6 a 0 -3 . For comparison, antimony metal, which has been reported − to exhibit an isomer shift between −11.3 and −11.95 mm/s, has a far more negative isomer shift than Yb 14 MnSb 11 and Eu 14 MnSb 11 .…”