Large whiskers of a new KAl9O14 polymorph
with mullite-type structure were synthesized. The chemical composition
of the crystals was confirmed by energy-dispersive X-ray spectroscopy,
and the structure was determined using single-crystal X-ray diffraction.
Nanosized twin domains and one-dimensional diffuse scattering were
observed utilizing transmission electron microscopy. The compound
crystallizes in space group P21/n (a = 8.1880(8), b =
7.6760(7), c = 8.7944(9) Å, β = 110.570(8)°, V = 517.50(9) Å3, Z = 2).
Crystals of KAl9O14 exhibit a mullite-type structure
with linear edge-sharing AlO6 octahedral chains connected
with groups of two AlO4 tetrahedra and one AlO5 trigonal bipyramid. Additionally, disproportionation of KAl9O14 into K β-alumina and corundum was observed
using in situ high-temperature optical microscopy and Raman spectroscopy.